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Filtering by: Creator Reilly, Paul Remove constraint Creator: Reilly, Paul Academic Affiliation Chemistry Remove constraint Academic Affiliation: Chemistry

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  • Rationalization and innovative design of asymmetric organocatalysts through computational investigation

    Creator:
    Johnston, Ryne Connell
    Abstract:
    My work on computing complex catalyzed organic transformations reveals that only a few subtle chemical factors, e.g. non-classical hydrogen bonding, (hyper)conjugation and steric effects, common across different catalyst manifolds are critical for catalysis and selectivity. Rational manipulation and exploitation of these factors has led to improved catalyst designs, which has...
    Resource Type:
    Dissertation
    Full Text:
    Organocatalysts through Computational Investigation. Abstract approved: Paul Ha-Yeon Cheong

  • Growth and characterization of wide–gap semiconducting oxide and chalcogenide thin films by pulsed laser deposition

    Creator:
    Newhouse, Paul F.
    Abstract:
    The preparation and characterization of thin film oxides and chalcogenides by pulsed laser deposition (PLD) is presented. An overview of fundamental PLD concepts are presented and are followed by a description implementation and development of the PLD systems at OSU. We present the results of thin film growth of high...
    Resource Type:
    Dissertation
    Full Text:
    AN ABSTRACT OF THE DISSERTATION OF Paul F. Newhouse for the

  • Studies toward the total synthesis of alkaloids : nagelamide A and D, agelastatin D, dragmacidin A-C, salacin and almazoles

    Creator:
    Tonsiengsom, Sorasaree
    Abstract:
    Studies toward the total syntheses of highly potent cytotoxic alkaloids including the bromopyrrole alkaloids and indole alkaloids were conducted and are described. Studies carried out in the course of this dissertation consist of five total syntheses of natural products that include bromopyrrole alkaloids nagelamide A, D and agelastatin D as...
    Resource Type:
    Dissertation
    Full Text:
    devoted to this research study. I would also like to thank Drs. Max Deinzer, Kevin Gable, Paul Blakemore

  • New Treatments for HIV and Cancer: Uncovering Bioactive Compounds from Small Molecule Sources

    Creator:
    Overacker, Ross D.
    Abstract:
    Small molecule drugs have been instrumental in our fight against diseases, beginning when some of the earliest ancient cultures used plant remedies to treat illnesses. More recently, the skill of isolating and characterizing the active ingredients within bioactive plants and microbial extracts has led to the isolation and design of...
    Resource Type:
    Dissertation
    Full Text:
    positivity, hard work, and determination are a model for all. I would like to thank Paul Blakemore for

  • Chronopotentiometry of Sm(II) and Pm(III) in molten LiCl-KCl eutectic

    Creator:
    Nixon, Richard Allen
    Abstract:
    Samarium (III) and promethium (III) were studied by chronopotentiometry in a molten LiCl-KC1 eutectic. Tungsten electrodes were used to avoid alloying effects encountered with platinum electrodes. Adsorption phenomena were observed which prevented the study of any kinetic effects. The quarter wave potentials were measured as: Sm(III) = 0.95 ± 0.05...
    Resource Type:
    Masters Thesis
    Full Text:
    is expressed to Professor Paul Delahay of New York University for his helpful consultation on ad

  • The effect of oxide impurity on the conductivity of potassium chloride

    Creator:
    Kouts, Daberath
    Abstract:
    Direct current conductivity measurements on KC1:O[superscript]= crystals were used to determine an enthalpy of 0.42 ev for the dissociation for anion-vacancy-oxide ion complex. The entropy of dissociation was found to be approximately -4x 10⁻⁴ev deg⁻¹. The intrinsic "activation" energy was found to be 1.91 ev as compared to 1.95 ev,...
    Resource Type:
    Masters Thesis
    Full Text:
    after six hours of growing time. This grow- ing procedure was developed by Paul (22). Coloration The

  • Aqueous chemistries for oxide electronics

    Creator:
    Meyers, Stephen T.
    Abstract:
    The variegated aqueous chemistries of metal cations are applied to the design and synthesis of non-toxic solution precursors suitable for additive printing of large-area oxide electronics. Polycondensation behaviors of aqueous Al+3 and PO4 +3 are manipulated in the deposition of atomically smooth amorphous aluminum oxide phosphate (AlPO) dielectric films. AlPO...
    Resource Type:
    Dissertation
    Full Text:
    , Chris Knutson, Alan Telecky, Sharon Betterton, and honorary Keszler group member Paul Newhouse have

  • Optimization by transfer function estimation of the galvanovoltammetric determination of dissolved chlorine in a flowing stream

    Creator:
    Miller, Clinton Earl
    Abstract:
    Optimization of the galvanovoltammetric determination of dissolved chlorine in a flowing stream was achieved through the use of an analog computational device and improvements in the design of the galvanovoltammetric cell and accompanying electronic circuitry. An analysis system, applicable to industrial use over a range of flow rates and dissolved...
    Resource Type:
    Masters Thesis
    Full Text:
    analysis. In: Advances in analytical chemistry and instrumentation, ed. by C. N. Reilly and F. W. Mc

  • Transpacific transport of benzo[a]pyrene emitted from Asia

    Creator:
    Zhang, Y., Tao, S., Ma, J., and Simonich, S.
    Abstract:
    A global-scale three dimensional atmospheric transport and chemistry model was applied to simulate transpacific transport of Benzo[a]pyrene (BaP) emitted from Asia. The model results were compared with observations at six monitoring sites. The annual mean and seasonal variation of transport patterns and the contributions of different Asian source regions to...
    Resource Type:
    Article

  • Electronic spectroscopy of biological relevant species and their complexes with solvent molecules

    Creator:
    He, Yonggang
    Abstract:
    In this dissertation, I present electronic spectroscopy of a few biologically relevant species and their complexes with solvent molecules in the gas phase using a variety of techniques, including resonantly enhanced multiphoton ionization (REMPI), laser induced fluorescence (LIF), and zero kinetic energy (ZEKE) photoelectron spectroscopy. My work on several methylated...
    Resource Type:
    Dissertation
    Full Text:
    . Smith, J. L. Knee, I Chem. Phys. 1992, 97, 2843. 12. X. Song, M. Yang, E. R. Davidson, J. P. Reilly, J