Few discoveries of any importance have been the result of a moment's happy coincidence; rather have they been the fruit of many hours of tedious thought and experiment. This is especially true in the realm of organic chemistry. Here, where progress is made only by the most painstaking experimentation, extensive...
We report the use of MIL-120 as a water-stable and cost-effective metal-organic framework (MOF) for selectively capturing CO₂ from wet flue gas. Synthesized using inexpensive and environmentally benign reagents in water, MIL-120 possesses one-dimensional pores decorated with hydroxyl-bridged Al(III) ions and benzene rings with an interstitial spacing of 4.78 Å....
Aqueous complexation of Th(IV), U(IV), Np(IV), Pu(III/IV), and Ce(III/IV) with DTPA was studied by potentiometry, absorption spectrophotometry, and cyclic voltammetry at 1 M ionic strength and 25 °C. The stability constants for the 1:1 complex of each trivalent and tetravalent metal were calculated. From the potentiometric data, we report stability...
The recent quest for improved functional materials like high permittivity dielectrics and/or
multiferroics has triggered an intense wave of research. Many materials have been checked for their
dielectric permittivity or their polarization state. In this report, we call for caution when samples are
simultaneously displaying an insulating behavior and a...
Isomerically pure cis,cis,trans-1-pheny1-1,3,5-
heptatriene was prepared and cyclized. Ring closure
was followed by a 1,5 hydrogen shift, and the only product
observed was 1-phenyl -6-methyl -1,3-cyclohexadiene.
Rough first order rate constants for thermolysis and
the hydrogen shift were determined. Kinetic estimates
indicate that the report of disallowed product in a...
The future of iron pnictide superconductors in technology is still undecided. While these materials are now known to possess high critical temperatures and critical magnetic fields processing methods for these materials are still in their infancy. Recently we have been investigating possible ways to speed up the synthetic process for...
We report on the effects of spin fluctuations, magnetic ordering, and external magnetic field on the
dielectric constant of the ferromagnet SeCuO₃, and the antiferromagnet TeCuO₃. A model based on the
coupling between uniform polarization and the q-dependent spin-spin correlation function is presented
to explain the different behaviors for these...
Radiation exposure to the brain can occur from a variety of events, including space missions, nuclear accidents, and clinical treatments. The effects of high dose radiation are well studied, but those of lower dosage are more elusive. Decline of memory and cognition is observed in patients exposed to low dose...