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A study of the infrared intensities of some small molecular anions

Creator:: Pastorek, Christine
Resource Type:: Dissertation
Full Text:: Pastorek, Christine AN ABSTRACT OF THE THESIS OF

Atropisomeric 8,8'-biquinolyl derivatives : synthesis, properties and applications

Creator:: Milicevic, Selena D.
Abstract:: 7,7'-Dihydroxy-8,8'-biquinolyl (azaBINOL) was prepared from 7-hydroxyquinoline via N,N-dimethyl O-quinol-7-yl carbamate by directed ortho-metallation followed by FeCl₃-mediated oxidative coupling of the 8-lithioquinoline intermediate. Saponification of the resulting dicarbamate provided crystalline (±)-azaBINOL in 56% overall yield. 6,6'-Bis(dimethylaminocarbonyl)-7,7'-dihydroxy-8,8´-biquinolyl was prepared from the same dicarbamate by a double anionic-Fries rearrangement in 43% yield. 7,7'-Bis(diethylamino-carbonyloxy)-6,6'-diiodo-8,8´-biquinolyl...
Resource Type:: Dissertation
Full Text:: thank Dr. Christine Pastorek for her help with UV analysis. I would like to thank Ms. Jacqui Colley

Synthesis of novel ambifunctional atropisomeric 2,2',6,6'-tetrasubstituted biphenyls and investigation of their properties and organocatalytic activity

Creator:: Sephton, Mark Alan
Abstract:: Ambifunctional axially chiral 2,2',6,6'-tetrasubstituted biphenyls containing nucleophilic (or basic) functional groups juxtaposed with hydrogen-bond donors were synthesized and their properties studied. Applications for the prepared biaryls as potential organocatalysts for enantioselective carbon-carbon bond forming reactions were examined. Processes investigated included: aldol, Michael, nitroaldol (Henry), and Baylis-Hillman reactions. The novel amidoamine...
Resource Type:: Dissertation
Full Text:: extend my appreciation to Dr. Emile Firpo and Dr. Christine Pastorek for their friendly interactions

Synthetic studies on the macrolide antibiotic rutamycin B

Creator:: Wang, Shan
Resource Type:: Dissertation
Full Text:: , No Soo Kim, Tae-song Kim, Nadine Lee, Mitch Nambu, Christine Nylund, Yoshihiro Ohba, Warren Porter

Synthesis and structure of transition metal siloxy compounds

Creator:: Huang, Mingdong
Resource Type:: Dissertation
Full Text:: help in X-ray diffraction study; to John Archibald, Roger Kohnert, and Christine Pastorek for the

Synthetic studies on necic acids of pyrrolizidine alkaloids

Creator:: Lee, Nadine Chauyi
Resource Type:: Dissertation
Full Text:: . Holoboski, Jorg Deerberg, Duncan J. Wardrop, Carla Hassler, Sung-Kee Kim, Christine S. Nylund, Scott J

Synthesis and study of transparent p- and n-type semiconductors and luminescent materials

Creator:: Park, Cheol-Hee
Abstract:: New transparent p- and n-type semiconductors and luminescent materials have been prepared and characterized. Synthesis, structures, optical and electrical properties of new chalcogenide fluoride p-type transparent semiconductors MCuQF (M=Ba, Sr; Q=S, Se, Te) are described. Band-gap tuning and improvement in conductivity through p-type doping are demonstrated in the family. The...
Resource Type:: Dissertation
Full Text:: . I am indebted to Dr. Joshep W. Nibler for his help with lifetime measurements and Dr. Christine

Expanding the scope of a Diels-Alder approach to biaryl synthesis

Creator:: Schwartz, Johanna Perkins
Abstract:: A Diels-Alder approach to biaryls (DAB) has been applied towards the synthesis of highly substituted, programmable biaryl templates. Tri- and tetra-ortho-substituted biaryls can be produced in just three to four steps from commercially available materials utilizing the Diels-Alder [4+2] cycloaddition. The methods described herein will illustrate the ability of mono...
Resource Type:: Dissertation
Full Text:: . William Martin for his continued friendship and advice, Emile Firpo and Dr. Christine Pastorek for their

New Graphite Intercalation Chemistry with Ethers and Amines

Creator:: Zhang, Hanyang
Abstract:: Novel donor-typed ternary graphite intercalation compounds (GICs) are synthesized and characterized containing (1) pyrrolidinium cations with DMSO co-intercalates; (2) alkali metal cations with crown ether co-intercalates; and (3) alkali metal cations with polyethylene glycol co-intercalates. Structural and compositional data are obtained for the stable products. A new ether-amine co-intercalate exchange...
Resource Type:: Dissertation
Full Text:: measurements, Dr. Christine Pastorek for assistance with GC-MS as well as letting me be her teaching

Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

Creator:: Jieratum, Vorranutch
Abstract:: The materials Fe₂(Si,Ge)(S,Se)₄, Cu₃PS[subscript 4-x]Se[subscript x] (0 ≤ x ≤ 4), and Cu₃PxAs[subscript 1-x]S₄ (0 ≤ x ≤ 1) have been synthesized and studied as new earth-abundant absorbers for single and multijunction photovoltaic cells as well as solar fuel generation. The synthesis, single-crystal growth, and optical and electrical properties of...
Resource Type:: Dissertation

ScholarsArchive@OSU

A study of the infrared intensities of some small molecular anions

Atropisomeric 8,8'-biquinolyl derivatives : synthesis, properties and applications

Synthesis of novel ambifunctional atropisomeric 2,2',6,6'-tetrasubstituted biphenyls and investigation of their properties and organocatalytic activity

Synthetic studies on the macrolide antibiotic rutamycin B

Synthesis and structure of transition metal siloxy compounds

Synthetic studies on necic acids of pyrrolizidine alkaloids

Synthesis and study of transparent p- and n-type semiconductors and luminescent materials

Expanding the scope of a Diels-Alder approach to biaryl synthesis

New Graphite Intercalation Chemistry with Ethers and Amines

Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

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