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Creator:: Mangalam, R. V. K., Smith, Andrew E., Boudin, S., McLoughlin, C., Subramanian, M. A., and Prellier, W.
Abstract:: The growth of YMn₀.₃₅In₀.₆₅O₃ thin films and their optical and magnetic behavior are reported. The YMn₀.₃₅In₀.₆₅O₃ thin film grows along the (0001) orientation with hexagonal structure similar to YMnO₃ on c-plane sapphire. The film shows paramagnetic behavior in the temperature range measured. The film exhibits a blue color due to...
Resource Type:: Article
Full Text:: behavior of YMn0.35In0.65O3 thin film R. V. K. Mangalam,1 Andrew E. Smith,2 S. Boudin,1 C. McLoughlin,1,3

Creator:: Sheets, W. C., Smith, A. E., Subramanian, M. A., and Prellier, W.
Abstract:: Epitaxial LaRh₁/₂Mn₁/₂O₃ thin films have been grown on (001)-oriented LaAlO₃ and SrTiO₃ substrates using pulsed laser deposition. The optimized thin film samples are semiconducting and ferromagnetic with a Curie temperature close to 100 K, a coercive field of 1200 Oe, and a saturation magnetization of 1.7μB per formula unit. The...
Resource Type:: Article
Full Text:: magnetic properties of LaRh1/2Mn1/2O3 thin films W. C. Sheets,1 A. E. Smith,2 M. A. Subramanian,2 and W

Creator:: Gould, Eoin, Walden, Daniel M., Kasten, Kevin, Johnston, Ryne C., Wu, Jiufeng, Slawin, Alexandra M., Mustard, Thomas J. L., Johnston, Brittany, Davies, Tony, Cheong, Paul Ha-Yeon, and Smith, Andrew D.
Abstract:: The regiodivergent O- to C- or N-carboxyl transfer of pyrazolyl carbonates is described, with DMAP giving preferential N-carboxylation and triazolinylidenes promoting selective C-carboxylation (both with up to >99 : 1 regioselectivity). An enantioselective O- to C-carboxyl variant using NHC catalysis is demonstrated (up to 92% ee), while mechanistic and DFT studies outline...
Resource Type:: Article
Full Text:: ., ... & Smith, A. D. (2014). Catalyst selective and regiodivergent O- to C- or N-carboxyl transfer of pyrazolyl

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