Index Catalog // ScholarsArchive@OSU

Using Computational Methods to Elucidate Reaction Mechanisms for Copper Catalyzed Reactions

Creator:: Caspary, Katherine E.
Abstract:: In this report, two studies are presented that utilize computations to predict and elucidate the reaction mechanisms of two different copper catalyzed reactions. Each study provides insight into the various chemical transformations, as well as the how and why behind regioselectivity and isotopic selectivity. The importance of this research is...
Resource Type:: Masters Thesis
Full Text:: 0.0 C F Cu FX N N -1.3 0.2 1.3 1.4 Cu L L O CF2X O G (k c a l/m o l) Reaction

The Local Structure of Functional Electroceramics

Creator:: Culbertson, Charles M.
Abstract:: This work investigates the relationship between the local structure and physical properties of a set of classical (MgTiO3, CaTiO3, SrTiO3, and BaTiO3) and complex ((1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3[BZT-BCT], Na0.5Bi0.5TiO3 [NBT]) perovskite electroceramics. The materials in this work were synthesized via standard solid state ceramic synthesis, the structure was investigated through a number of...
Resource Type:: Dissertation
Full Text:: Absorption Fine Structure (EXAFS) from M. Blank, reproduced with permission under CC BY-SA 3.0

Enigmatic Quantum Materials: Novel Spin-Orbit Coupled 4d/5d Metal Oxides and Intermetallics

Creator:: Wallace, Maxwell K.
Resource Type:: Dissertation
Full Text:: “honeycomb” layered oxides, where A is an alkali atom and M is a 4d or 5d element, show unique electronic

Atropisomeric 8,8'-biquinolyl derivatives : synthesis, properties and applications

Creator:: Milicevic, Selena D.
Abstract:: 7,7'-Dihydroxy-8,8'-biquinolyl (azaBINOL) was prepared from 7-hydroxyquinoline via N,N-dimethyl O-quinol-7-yl carbamate by directed ortho-metallation followed by FeCl₃-mediated oxidative coupling of the 8-lithioquinoline intermediate. Saponification of the resulting dicarbamate provided crystalline (±)-azaBINOL in 56% overall yield. 6,6'-Bis(dimethylaminocarbonyl)-7,7'-dihydroxy-8,8´-biquinolyl was prepared from the same dicarbamate by a double anionic-Fries rearrangement in 43% yield. 7,7'-Bis(diethylamino-carbonyloxy)-6,6'-diiodo-8,8´-biquinolyl...
Resource Type:: Dissertation
Full Text:: symmetric cleavage) and the ion at m/z 255 was identified with the unusual ion 33, not found in other

Large-D limit for correlation methods in atoms

Creator:: Summerfield, John H.
Resource Type:: Dissertation
Full Text:: facile. For clar- ity, we temporarily reintroduce h and m (both of which are unity in atomic units) so

Stationary electrode voltammetry and chronoamperometry in an alkali metal carbonate-borate melt

Creator:: Petcoff, Darrell George
Abstract:: The electrochemistry of the lithium-potassium-sodium carbonate-borate melt was explored by voltammetry and chrono-amperometry. In support of this, a controlled-potential polarograph and associated hardware was constructed. Several different types of reference electrodes were tried before choosing a porcelain membrane electrode containing a silver wire immersed in a silver sulfate melt. The...
Resource Type:: Dissertation
Full Text:: polarograms for .004 M niobium Pa e 39. in LiCl-KC1 eutectic at 450°C. 158 40. Voltammograms for copper (II

The study of the influence of the nitro substituent on the hydrazinolysis of certain substituted 5-nitropyrimidines

Creator:: Stahl, Quade Russell
Abstract:: The unique reaction between 4, 6-dimethoxy-5-nitropyrimidine and methylhydrazine was investigated. The reaction product was identified as 4-hydrazino-6-hydroxypyrimidine from (a) spectral data, (b) by direct synthesis of the product via 4-chloro-6-hydroxypyrimidine and hydrazine, and (c) by conversion of the product to the known 4-amino-6-hydroxypyrimidine using Raney nickel. The product was not...
Resource Type:: Dissertation
Full Text:: further investigation. The yellow-tan to light brown precipitate 2H-K was recrystal- lized from water m

Reactions of tertiary phosphites with alkyl iodides in acetonitrile

Creator:: Goodell, Lane Joseph
Resource Type:: Masters Thesis
Full Text:: , infrared and n. m. r. spectroscopy, and gas liquid chromatography. The reactions were conducted in a

A kinetic investigation of the hydrolysis of trimethylamine-sulfur trioxide in dimethyl sulfoxide-water solvents

Creator:: Johnson, William Allen
Resource Type:: Dissertation
Full Text:: zero for 6 the standard solvent, 80% methanol in water. Variable m depends on the substance

The mechanisms of some reactions of thiolsulfinates (sulfenic anhydrides)

Creator:: Venier, Clifford George
Resource Type:: Dissertation
Full Text:: . 00859 M 40 0. 230 0.0503 40 0. 878 0.1000 40 1.37 0.00756 60 1.14 0.01802 60 1.70 0.0400 60

ScholarsArchive@OSU

Using Computational Methods to Elucidate Reaction Mechanisms for Copper Catalyzed Reactions

The Local Structure of Functional Electroceramics

Enigmatic Quantum Materials: Novel Spin-Orbit Coupled 4d/5d Metal Oxides and Intermetallics

Atropisomeric 8,8'-biquinolyl derivatives : synthesis, properties and applications

Large-D limit for correlation methods in atoms

Stationary electrode voltammetry and chronoamperometry in an alkali metal carbonate-borate melt

The study of the influence of the nitro substituent on the hydrazinolysis of certain substituted 5-nitropyrimidines

Reactions of tertiary phosphites with alkyl iodides in acetonitrile

A kinetic investigation of the hydrolysis of trimethylamine-sulfur trioxide in dimethyl sulfoxide-water solvents

The mechanisms of some reactions of thiolsulfinates (sulfenic anhydrides)

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