Index Catalog // ScholarsArchive@OSU

Hydrogen abstractions from arylmethanes

Creator:: Unruh, Jerry Dean
Abstract:: The relative rates of hydrogen abstraction from a series of 13 arylmethanes by the trichloromethyl radical were determined at 70°. The attacking radical was generated from bromotrichloromethane us ing benzoyl peroxide as the initiator. The solvent was benzenebromotrichloromethane. An excellent correlation, with a coefficient of 0.977, was obtained when the...
Resource Type:: Dissertation
Full Text:: THE THESIS OF JERRY DEAN UNRUH (Name) for the DOCTOR OF PHILOSOPHY in ORGANIC CHEMISTRY presented

The purification and characterization of a soluble mitochondrial adenosinetriphosphatase from cabbage, Brassica oleracea

Creator:: Petersen, Thomas Gordon
Resource Type:: Masters Thesis
Full Text:: AN ABSTRACT OF THE THESIS OF- Thomas Gordon Petersen for

Time-of-flight scattering and recoil spectrometry (TOF-SARS) applied to molecular liquid surfaces : a new approach to surface composition and orientation

Creator:: Gannon, Thomas J.
Abstract:: In spite of their importance in many systems, liquid surfaces have been explored at the microscopic level to a much lesser extent than solids. Most surface analysis must take place in vacuum, a major drawback for liquids. The technique of time-of-flight scattering and recoil spectrometry (TOF-SARS) has been applied to...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE THESIS OF Thomas J. Gannon for the degree

Hydrogen atom abstraction from saturated cyclic ethers and sulfides

Creator:: Hallen, Richard Thomas
Resource Type:: Masters Thesis
Full Text:: Sulfides AN ABSTRACT OF THE THESIS OF RICHARD THOMAS HALLEN for the degree of MASTER OF SCIENCE in

Reactions of organoboranes

Creator:: Thompson, Thomas Myron
Abstract:: An examination was made of some reactions involving a transfer of carbon from boron to carbon. In the case of the reaction of a C[subscript n] alkylorganoborane with dichlorocarbene the intermediate was a C[subscript n]₊₁ chloroalkylorganoborane. Oxidation of this intermediate yielded an homologous acid (33%) and the usual alcohol (66%)....
Resource Type:: Masters Thesis
Full Text:: Thomas Myron Thompson for the M. S. in Chemistry (Organic) (Name) (Degree) (Major) Date thesis is

Formation of alkyl-and dialkylcarbenes. The 3-cyclohexenyl carbinyl carbene system

Creator:: Crouse, Dale McClish
Abstract:: The 3-cyclohexenyl carbinyl carbene species was formed by the thermal decomposition of the p-toluenesulfonylhydrazone sodium salt and by oxidation of the hydrazone. Several oxidizing agents were studied. The products were investigated under aprotic and protic conditions and at various temperatures. The diazocompound was formed as an intermediate and found to...
Resource Type:: Masters Thesis
Full Text:: Gwendolyn Hansen ACKNOWLEDGEMENTS I wish to express my appreciation to Dr. F. Thomas Bond for his

Conformation and reactivity studies of some bicyclo(3.3.1) nonane derivatives

Creator:: Sturmer, David Michael
Abstract:: New syntheses for 2-bicyclo(3.3.1)nonanone and 7-bicyclo-(3.3.1)nonen-2-one were developed. The saturated ketone was prepared from phenol and acrylonitrile via a novel intramolecular S[subscript N]2 cyclization process. A Friedel-Crafts cyclization of 3-(3-cyclohexenyl)propanoyl chloride permitted synthesis of the unsaturated ketone from 4-cyclohexene carboxaldehyde. The formation of the bicyclo(3.3.1)nonane rather than a bicyclo(3.2.2)nonane skeleton...
Resource Type:: Dissertation
Full Text:: . Comparative n. m. r. spectra for reduced Friedel- Crafts ketone (A), authentic 2-bicyclo(3.2.2)- nonanone

Some synthetic efforts in small ring chemistry

Creator:: Lam, Luke Kwok Tung
Abstract:: Cyclopropylcyclobutene was prepared via the intermediate dicyclopropylcarbinyl carbene which was generated by the thermal decomposition of the sodium salt of dicyclopropylketone p-toluenesulfonylhydrazone. The successive thermal isomerization of cyclopropylcyclobutene to 2-cyclopropyl-1, 3-butadiene and to vinylcyclopentene was studied. Kinetic data were obtained for the cyclopropylcyclobutene to 2-cyclopropyl-1, 3-butadiene isomerization in the gas...
Resource Type:: Masters Thesis
Full Text:: . Thomas Bond Cyclopropylcyclobutene was prepared via the intermediate dicyclopropylcarbinyl carbene

Steroid dialkylcarbene reactions

Creator:: Dixon, Dale David
Abstract:: Steroid carbenes have been investigated as synthetic intermediates. Basic decomposition of 4-en-3-one tosylhydrazones (and other A-ring systems) gives varying amounts of 2, 4-dienes, and solvent derived products with diglyme, heptane, tetrachloroethylene, carbon tetrachloride, benzene and cyclohexene. A method for separating complex product mixtures was developed and a study of the...
Resource Type:: Dissertation
Full Text:: express my appreciation to Dr. F. Thomas Bond for his instruction, encouragement, and scientific

Reactions of tertiary phosphites with alkyl iodides in acetonitrile

Creator:: Goodell, Lane Joseph
Resource Type:: Masters Thesis
Full Text:: -phosphorus bond. (RO)3P + R'X 1 [(RO)3PR')X],-- (RO)2P(0)R' + RX The intermediate might have a salt -like

ScholarsArchive@OSU

Hydrogen abstractions from arylmethanes

The purification and characterization of a soluble mitochondrial adenosinetriphosphatase from cabbage, Brassica oleracea

Time-of-flight scattering and recoil spectrometry (TOF-SARS) applied to molecular liquid surfaces : a new approach to surface composition and orientation

Hydrogen atom abstraction from saturated cyclic ethers and sulfides

Reactions of organoboranes

Formation of alkyl-and dialkylcarbenes. The 3-cyclohexenyl carbinyl carbene system

Conformation and reactivity studies of some bicyclo(3.3.1) nonane derivatives

Some synthetic efforts in small ring chemistry

Steroid dialkylcarbene reactions

Reactions of tertiary phosphites with alkyl iodides in acetonitrile

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