Index Catalog // ScholarsArchive@OSU

Studies relating to the preparation and properties of perfluoroalkyl substituted boranes

Creator:: Gritton, George Vance
Resource Type:: Masters Thesis
Full Text:: AN ABSTRACT OF THE THESIS OF George Vance Gritton for the M

Stereoselective synthesis & application of enantioenriched main group α-haloalkyl organometal reagents

Creator:: Emerson, Christopher R.
Abstract:: Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes. Abstract for...
Resource Type:: Dissertation

Broadening the scope of the modified-Julia reaction : a mild and stereoselective method for the synthesis of (Z)-configurated α,β-unsaturated lactones

Creator:: Giesbrecht, Heath Eugene
Abstract:: An intramolecular variant of the modified-Julia olefination was demonstrated by the synthesis of α,β-unsaturated lactones in a mild and (Z)-selective fashion. The lynchpin reagent (benzothiazol-2-sulfonyl) acetic acid was synthesized in a straightforward fashion in 86% overall yield from commercially available 2-mercaptobenzothiazole via conversion to ethyl (benzothiazol-2-ylthio)acetate by base mediated alkylation...
Resource Type:: Masters Thesis
Full Text:: )-Configurated α,β- Unsaturated Lactones Abstract approved: Paul R. Blakemore An intramolecular

A comparison of intact protein with amino acid mixtures in protein nutrition

Creator:: Snippper, Lawrence Paul
Resource Type:: Dissertation
Full Text:: LAWRENCE PAUL SNIPPER A THESIS submitted to OREGON STATE COLLEGE in partial fulfillment of the

Condensation of crotonic and tiglic acids with aldehydes and ketones

Creator:: Johnson, Paul Robert
Resource Type:: Masters Thesis
Full Text:: and ketones AN ABSTRACT OF THE THESIS OF Paul Robert Johnson for the degree of Master of Science in

Searching for new niobium oxide based superconductors

Creator:: Bacon, Paul Eric
Resource Type:: Masters Thesis
Full Text:: ABSTRACT OF THE THESIS OF Paul Eric Bacon for the degree of Master of Science in Chemistry presented on

Progress Towards the Total Synthesis of Bazzanin K

Creator:: Salvo, Patrick
Abstract:: Molecular chirality plays a critical role in chemistry, biology, and medicine. To study and better understand conformational chirality, it is necessary to obtain structurally interesting molecules that exhibit this form of chirality. Our lab utilizes total synthesis and methodological development to obtain conformationally chiral natural products of interest. We believe...
Resource Type:: Masters Thesis
Full Text:: ., 2003, 42, 730—765. 10 K. C. Nicolaou, H. J. Mitchell, N. F. Jain, N. Winssinger, R. Hughes, and

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

Creator:: Vellucci, Jessica K.
Abstract:: Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
Resource Type:: Dissertation
Full Text:: Robinson, C. H.; Gonj, O.; Mitchell, A.; Oliveto, E. P.; Barton, D. H. R. Tetrahedron 1965, 21, 743. 18

The development of aminal radicals for the synthesis of nitrogen-rich natural products

Creator:: Schiedler, David A.
Abstract:: Organic compounds which contain one or more nitrogen atoms are especially important as they are disproportionately represented among biologically active molecules. As a result, significant effort has been focused on the development of methods for the synthesis of nitrogenous molecules. We identified the aminal as an under-explored functional group. Despite...
Resource Type:: Dissertation
Full Text:: .; Brookes, P. J. Chem. Soc. Perkin Trans. 1 2000, 1–14. (d) Mitchell, E. A.; Peschiulli, A.; Lefevre, N

Part I: Synthetic Studies Toward Mandelalide A and Madeirolide A; Part II: Synthesis of Mandelalide/Madeirolide Hybrid Structures

Creator:: Li, Jinming
Abstract:: Mandelalide A has attracted considerable interest from the synthetic community due to its intriguing structure and important cytotoxic activity. Madeirolide A, a structurally related macrolide, shows promising antifungal activity but no appreciable anticancer activity. This dissertation describes synthetic studies toward mandelalide A, madeirolide A and their hybrid structures. Part I...
Resource Type:: Dissertation
Full Text:: all my graduate studies. I would also like to thank my graduate committee members, Professor Paul

ScholarsArchive@OSU

Studies relating to the preparation and properties of perfluoroalkyl substituted boranes

Stereoselective synthesis & application of enantioenriched main group α-haloalkyl organometal reagents

Broadening the scope of the modified-Julia reaction : a mild and stereoselective method for the synthesis of (Z)-configurated α,β-unsaturated lactones

A comparison of intact protein with amino acid mixtures in protein nutrition

Condensation of crotonic and tiglic acids with aldehydes and ketones

Searching for new niobium oxide based superconductors

Progress Towards the Total Synthesis of Bazzanin K

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

The development of aminal radicals for the synthesis of nitrogen-rich natural products

Part I: Synthetic Studies Toward Mandelalide A and Madeirolide A; Part II: Synthesis of Mandelalide/Madeirolide Hybrid Structures

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