Oxo-hydroxo Group 5 metal clusters are an untapped resource to study and advance aqueous solution processing of metal oxide thin films. The tetramethylammonium (TMA) hexatantalate salt (TMA6[H2Ta6O19]) yields dense Ta2O5 films (~95% of the bulk ß-Ta2O5 density) with atomically smooth surfaces (<4 Å root mean square surface roughness). This same...
Through passive adaptation to incidental flow, flexible aerodynamic surfaces exploit effects of increased lift, delayed stall and disturbance rejection. Wings of birds, bats, and insects exhibit these passive effects, and at the same time through the use of structural state feedback sensed from the loads on the wing, active control...
Microchannel process technology (MPT) offers several advantages to the field of nanomanufacturing: 1) improved process control over very short time intervals owing to shorter diffusional distances; and 2) reduced reactor size due to high surface area to volume ratios and enhanced heat and mass transfer. The objective of this thesis...
Tensegrity structures are composed of pure compressional elements that are connected via a network of pure tensional elements. The concept of tensegrity promises numerous advantages to the field of robotics. Tensegrity robots are, however, notoriously difficult to control due to their oscillatory nature and nonlinear interaction between the components. Multiagent...
Customer requirements and engineering specifications will influence the direction of the design in any product, so it is crucial to make the requirements as stable as possible so quality designs can be produced on time within a budget. It would be optimal for requirements and specifications to remain constant but...
Direct red Solid Oxide Fuel Cell (SOFC) Turbine hybrid plants have the potential to dramatically increase power plant efficiency, decrease emissions, and provide fast response to transient loads. The US Department of Energy's (DOE) Hybrid Performance Project is an experimental hybrid SOFC plant, built at the National
Energy Technology Laboratory...
Autonomous multiagent teams can be used in complex exploration tasks to both expedite the exploration and improve the efficiency. However, use of multiagent systems presents additional challenges. Specifically, in domains where the agents' actions are tightly coupled, coordinating multiple agents to achieve cooperative behavior at the group level is difficult....
Recent advancements in joining operations and additive manufacturing now allow complex metal parts to be built up from raw materials, as opposed to being machined down from solid blocks. This not only opens up the design space, but also allows for much more efficient manufacturing. By decomposing a complex part...
Changes in the global climate and forest management practices have given rise to increasing numbers and severity of wildfires. More than five million acres burned in the United States in 2017, while in Canada 7.4 million acres burned. In particular, an increasing amount of dead woody biomass is a key...
In Intense Pulsed Light (IPL) sintering, pulsed large-area visible light from a xenon lamp is absorbed by nanoparticle films or patterns and converted to heat, resulting in rapid sintering of the nanoparticles. This work experimentally characterizes IPL sintering of silver nanoparticle films. A newly observed turning point in the evolution...