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Filtering by: Creator Wynne, Clive D. Advisor Blakemore, Paul Degree Field Chemistry

Stereoselective synthesis & application of enantioenriched main group α-haloalkyl organometal reagents

Creator:

Emerson, Christopher R.

Abstract:

Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes. Abstract for...

Resource Type:

Dissertation