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Filtering by: Creator Kaufman, Diane Remove constraint Creator: Kaufman, Diane Advisor Bond, F. Thomas Remove constraint Advisor: Bond, F. Thomas

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  • Formation of alkyl-and dialkylcarbenes. The 3-cyclohexenyl carbinyl carbene system

    Creator:
    Crouse, Dale McClish
    Abstract:
    The 3-cyclohexenyl carbinyl carbene species was formed by the thermal decomposition of the p-toluenesulfonylhydrazone sodium salt and by oxidation of the hydrazone. Several oxidizing agents were studied. The products were investigated under aprotic and protic conditions and at various temperatures. The diazocompound was formed as an intermediate and found to...
    Resource Type:
    Masters Thesis

  • Steroid dialkylcarbene reactions

    Creator:
    Dixon, Dale David
    Abstract:
    Steroid carbenes have been investigated as synthetic intermediates. Basic decomposition of 4-en-3-one tosylhydrazones (and other A-ring systems) gives varying amounts of 2, 4-dienes, and solvent derived products with diglyme, heptane, tetrachloroethylene, carbon tetrachloride, benzene and cyclohexene. A method for separating complex product mixtures was developed and a study of the...
    Resource Type:
    Dissertation