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Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Creator:: Balyeat, John Robert
Abstract:: The tosylhydrazones of exo-3-deuteriocamphor and 2- deuterio-2,4-dimethy1-3-pentanone were treated with Nbromosuccinimide (NBS) and pyruvic acid to regenerate the parent ketones. The ketones from the pyruvic acid cleavage show a significant loss of deuterium. The ketones from the NBS cleavage show no loss of deuterium, indicating that stereochemical integrity at. C[subscript...
Resource Type:: Masters Thesis
Full Text:: - selectivity. Carbene Chemistry. I. Stereochemical Integrity at Ca in Ketone Tosylhydrazones. II. Hydrogen

Reactive intermediates : I. The mechanisms of photodehalogenation of three tetrachloronaphthalenes : II. Structure and electronic effects in some selected carbenes

Creator:: Clapp, Gary E.
Resource Type:: Dissertation
Full Text:: Reactive intermediates : I. The mechanisms of

The photodebromination of polybromobenzenes

Creator:: Couch, Tara Lin
Resource Type:: Dissertation
Full Text:: Dean of Graduate School I understand that my thesis will become part of the permanent collection of

The chemistry of selected carbene and radical ion intermediates

Creator:: Pugh, James K.
Resource Type:: Dissertation
Full Text:: : Major Professor, representing Chemistry Ch f Department of Chemistry D I understand that my thesis

The photochemistry of some insect juvenile hormone analogs

Creator:: Siggel, Lorenz
Abstract:: The photochemistry of some analogs of insect growth regulators (IGR's) was studied. Methyl geranate, TY, was synthesized and the mechanisms of its photochemical reaction pathways were studied by a variety of techniques. Direct irradiation of 71 in ether leads to the formation of five new products: 98, the product of...
Resource Type:: Dissertation
Full Text:: stronger." F. Nietsche In looking back over the five years that I have spent at OSU I've come to realize

The photochemistry of some polyhalobenzenes

Creator:: Huang, Yo-hsin
Resource Type:: Masters Thesis
Full Text:: Jonas for Yo-Hsin Huang ACKNOWLEDGMENT I would like to thank Professor Peter K. Freeman for his

Delocalization in cationic, carbene, and radical intermediates in some bridged polycyclic systems

Creator:: Dacres, Jelena Estelle
Resource Type:: Dissertation
Full Text:: February 7, 2001. APPROVED: Major Professor, representing Chair ofh& Department of Chemistry Dean I

A study of the chemistry of diisopropyl-, cyclopropylisopropyl-, and dicyclopropylcarbene

Creator:: Wuerch, Stephen E.
Abstract:: The effect of the conjugation with cyclopropyl rings on the activation parameters for the formation of carbenes from the corresponding diazo compounds was investigated using diisopropylcarbene (46), cyclopropyl-isopropylcarbene (47), and dicyclopropylcarbene (48). Each of these three carbenes was generated by the thermolysis of the parent benzenesulfonylhydrazone potassium salts using DMSO...
Resource Type:: Masters Thesis
Full Text:: and Dr. T. Darrah Thomas ACKNOWLEGDEMENT I am indeed very fortunate to have had an enthusiastic

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

Creator:: Raghavan, Ramaswamy Srinivasa, 1941-
Resource Type:: Dissertation
Full Text:: on c4- I c #7 I (Date) Title: REACTIVE INTERMEDIATES IN THE TRICYCLO- [3. 2. 1.02' 4]0C TANE RING

Divalent carbon intermediates in some bridged polycyclic compounds

Creator:: Hardy, Thomas A.
Resource Type:: Dissertation
Full Text:: her infinite support and under- standing. TABLE OF CONTENTS INTRODUCTION PART I

ScholarsArchive@OSU

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Reactive intermediates : I. The mechanisms of photodehalogenation of three tetrachloronaphthalenes : II. Structure and electronic effects in some selected carbenes

The photodebromination of polybromobenzenes

The chemistry of selected carbene and radical ion intermediates

The photochemistry of some insect juvenile hormone analogs

The photochemistry of some polyhalobenzenes

Delocalization in cationic, carbene, and radical intermediates in some bridged polycyclic systems

A study of the chemistry of diisopropyl-, cyclopropylisopropyl-, and dicyclopropylcarbene

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

Divalent carbon intermediates in some bridged polycyclic compounds

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