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Filtering by: Advisor Gleicher, Gerald Jay Date issued sim 1980-12-10

Molecular orbital correlation of the relative rates of chlorine atom abstraction from homo- and heteroarylmethyl chlorides by triphenyltin radical

Creator:

Soppe-Mbang, Helene

Abstract:

A series of momochloromethyl arenes and heteroarenes have been reacted with triphenyltin hydride at 70° C. Under these radical conditions the only observable reaction is reduction of the starting material to arylmethane or heteroarylmethane. A significant range of relative rates (a factor of eighty) has been found among the compounds...

Resource Type:

Dissertation