Nanostructured ZnO films were obtained via thermal oxidation of thin films formed with metallic Zn-nanoparticle dispersions. Commercial zinc nanoparticles used for this work were characterized by microscopic and thermal analysis methods to analyze the Zn-ZnO core shell structure, surface morphology and oxidation characteristics. These dispersions were spin-coated on SiO₂/Si substrates...
The motivation for undertaking this research was to increase the understanding of processing colloidal semiconductor nanocrystals and thin films metallic glasses to enable their wider application in future devices. This research covered two unique materials, lead selenide (PbSe) nanocrystals and thin film metallic glass alloy of zirconium copper aluminum nickel...
The development of solution-based methods for deposition of different thin film material is presented as an alternative to high cost vacuum-based methods. For certain materials, vacuum techniques are unsuitable for processing. Additionally, vacuum-based processes present high capital costs associated with equipment, and slow processing times. Atmospheric pressure solution based techniques...
Metal-organic frameworks (MOFs) are crystalline porous material distinguished for high free empty volume and pore tunability. MOF-74(Ni) was previously shown to be effective in adsorbing carbon dioxide, methane, and hydrogen. Microwave-assisted synthesis of MOF-74(Ni) was shown to lower reaction time from days to hours. In this thesis, experimental conditions of...
The need for less toxic quantum dots (QDs) has led to a significant number of investigations related to copper indium sulfide (CIS) QDs. Lower toxicity and broad band absorbance width makes CIS QDs appealing for light emitting diodes (LEDs), lasers, sensors, bio-imaging, solar cells, and computing. The optical and electronic...
Surface characterization of materials is widely utilized over a range of disciplines and essential to the development of new materials, technology, or processes. Metal oxide nanoclusters have shown promise as potential new generation photoresist materials for extreme ultraviolet (EUV) nanolithography. Organotin clusters have been proposed as potential candidates for resist...
In this work, colloidal PbSe quantum dots (QDs) are shown to be synthesized in a controlled manner by changing the growth time and reaction temperature in a microwave synthesis method. It is explained why quantum dots make such a unique material to create electronic devices and the specific benefits that...
Amorphous metal thin films (AMTFs) are of growing interest due to their unique mechanical properties and chemical stability. AMTFs have an advantage over polycrystalline metal films due to the lack of grain boundaries which gives AMTFs added durability and relatively smoother surfaces. For this reason, AMTFs have been investigated as...