A sensitive technique for the determination of As(III) and As{V)
at μ/L and sub-μg/L concentrations from a single sample aliquot
has been developed. This technique is based on the hydride
generation atomic absorption (HGAA) spectrophotometry. The hydrides
of the arsenic species are generated in a reaction vessel by mixing
the...
At Site-300, Lawrence Livermore National Laboratory (LLNL), CA,
trichloroethene (TCE) is present along with tetraalkoxysilanes such as tetrabutoxysilane
(TBOS) and tetrakis(2-ethylbutoxy) silane (TKEBS), as subsurface contaminants.
Intrinsic transformation of TCE to cis-dichloroethene (c-DCE) was observed in the
groundwater at locations co-contaminated with TBOS or TKEBS. Attenuation of TBOS
and TKEBS...
A practical and versatile instrument has been developed both to
optimize the chemistry of bio- and chemiluminescence reactions and to
measure ultra-trace quantities of associated analytes. The instrument
consists of a pneumatic flow injection system linked to a detection cell and a
signal processing and readout system. The disk-like cell...
A fiber optic fluorometer utilizing a double-fiber optic probe
was constructed. The absolute fluorescence signal and effective
collection efficiency are approximately one fifth those of typical
cuvette fluorometers and agree with those predicted by theory. A
quinine sulfate calibration curve shows linearity from a detection
limit of 10 pg/mL to...