Index Catalog // ScholarsArchive@OSU

Valence tautormerism in cis-1, 2-di-1'-cyclohexen-1'-ylethylene

Creator:: Pippin, Wallace Harold
Resource Type:: Masters Thesis

Thermal valence isomerization of trienes

Creator:: Polston, Norman Lee
Resource Type:: Masters Thesis

The synthesis and spectral properties of 2,4-dioxabicyclo [3.3.1] nonanes

Creator:: Provant, Stephen Glenn
Abstract:: 3-Methyl-2,4-dioxabicyclo [3.3.1] nonane and 7-hydroxy-3-methyl-2, 4-dioxabicyclo [3.3.1] nonane were synthesized by the method of Croxall, Glavis and Neher, although in low yields. The structure of both compounds was proven by analytical methods and analysis of their spectral properties. Tentative configuration of C-3 in both compounds was assigned on the assumption...
Resource Type:: Masters Thesis

The preparation of 2-methoxy-4,5-dimethylstilbene and its photochemistry

Creator:: Tong, Homer Hin-Chau
Abstract:: During a study of the abnormal dienone-phenol rearrangement discovered by Marvell and Geiszler, Imel (1960) found that 4-oxo-3,3-dimethyl-3,4-dihydrophenanthrene rearranged slowly to a phenol which was tentatively identified as 3,4-dimethyl-l-phenanthrol; further evidence to support this assignment was deemed essential. The recent work by Mallory on the photochemical conversion of stilbenes to...
Resource Type:: Masters Thesis

Synthesis of some bicyclo[6.1.0] - nonane derivatives

Creator:: Wall, Robert Gene
Abstract:: Bicyclo [6.1.0] non-4-ene was prepared by two routes; (1) reaction of cis-cis-1, 5-cycloöctadiene with methylene iodide and zinc-copper couple, (2) sodium-methanol reduction of 9, 9-dibromobicyclo-[6.1.0] non-4-ene. The bicyclononene was characterized by its infrared spectrum, nuclear magnetic resonance spectrum and common physical properties. The olefin was hydrogenated to bicyclo [6.1.0] -...
Resource Type:: Masters Thesis

Studies on the mechanism of formation of n-phenylpyridinium salts from 1,7-diaza-1,3,5-heptatrienes

Creator:: Shahidi, Iraj Khatib
Resource Type:: Dissertation

Some studies relating to the stereochemistry of the Claisen rearrangement of cis- and trans-α ,γ- dimethylallyl phenyl ethers

Creator:: Ong, Josephine
Resource Type:: Dissertation

Some features influencing the valence isomerism of cis-dienones to α-pyrans

Creator:: Gosink, Thomas A. (Thomas Anthony)
Resource Type:: Dissertation

Semihydrogenation in conjugated systems and its application in the synthesis of trienes

Creator:: Tashiro, John Toshiyuki
Resource Type:: Dissertation

Preparation of propylcyclohexanes with functions on the 4 and 3' positions

Creator:: Rowell, Charles Frederick
Abstract:: The preparation of 4-(3-hydroxypropyl) cyclohexanone and of 4-(3-hydroxypropyl) cyclohexene and a number of their derivatives as potential precursors of asymmetrically substituted bicyclo [3, 3, 1] nonanes is described. The ketone, 4-(3-hydroxypropyl) cyclohexanone, was prepared from p-allylanisole by three different routes. Common to each route was an initial hydroboration-oxidation followed by...
Resource Type:: Dissertation

Preparation and semihydrogenation of some a, β-acetylenic ketones

Creator:: Churchley, Philip Leslie
Resource Type:: Masters Thesis

Kinetic studies of some thermal rearrangements

Creator:: Schatz, Bruce Stewart
Resource Type:: Dissertation

Isolation and identification of certain toxic compounds in a fraction of Kraft mill waste

Creator:: Wiman, Robert Edgar, 1933-
Resource Type:: Dissertation

Identification of a product of the Friedel-Crafts cyclization of β -(3- cyclohexenyl) propionyl chloride

Creator:: McEwen, Terry Earl
Abstract:: An improved procedure for the preparation of β-(3-cyclohexenyl) propionic acid from 4-vinylcyclohexene was developed. The Friedel-Crafts cyclization of β-(3-(3-cyclohexenyl) propionyl chloride with aluminum chloride was shown to give one bicyclic chlorine containing ketone in 41% yield. This ketone was identified by a combination of spectral and chemical methods as a...
Resource Type:: Masters Thesis

I. Isolation of certain toxic components of kraft mill waste and attempts to determine their structure. ; II. Studies of the mechanism of the cope rearrangement of 1,2-divinyl-1, 2-cyclohexanediol

Creator:: Banks, Richard Charles
Abstract:: PART I. A chemical examination of the materials toxic to fish in kraft pulp mill wastes has been made as part of a water pollution study. Thirty gallons of "foul condensate" from a typical kraft mill gave 14 g of organic material when extracted with methylene chloride, and an additional...
Resource Type:: Dissertation

A study of the acid catalyzed rearrangement of 4-oxo-3, 3-dimethyl-3, 4-dihydrophenanthrene

Creator:: Imel, Arthur Madison
Resource Type:: Dissertation

A reinvestigation of the Claisen rearrangement of allyl o-tolyl ether

Creator:: Richardson, Bruce Coburn
Resource Type:: Dissertation

ScholarsArchive@OSU

Valence tautormerism in cis-1, 2-di-1'-cyclohexen-1'-ylethylene

Thermal valence isomerization of trienes

The synthesis and spectral properties of 2,4-dioxabicyclo [3.3.1] nonanes

The preparation of 2-methoxy-4,5-dimethylstilbene and its photochemistry

Synthesis of some bicyclo[6.1.0] - nonane derivatives

Studies on the mechanism of formation of n-phenylpyridinium salts from 1,7-diaza-1,3,5-heptatrienes

Some studies relating to the stereochemistry of the Claisen rearrangement of cis- and trans-α ,γ- dimethylallyl phenyl ethers

Some features influencing the valence isomerism of cis-dienones to α-pyrans

Semihydrogenation in conjugated systems and its application in the synthesis of trienes

Preparation of propylcyclohexanes with functions on the 4 and 3' positions

Preparation and semihydrogenation of some a, β-acetylenic ketones

Kinetic studies of some thermal rearrangements

Isolation and identification of certain toxic compounds in a fraction of Kraft mill waste

Identification of a product of the Friedel-Crafts cyclization of β -(3- cyclohexenyl) propionyl chloride

I. Isolation of certain toxic components of kraft mill waste and attempts to determine their structure. ; II. Studies of the mechanism of the cope rearrangement of 1,2-divinyl-1, 2-cyclohexanediol

Attempts to prepare cis-a, 2-dicyclohexenylethylene

An investigation of the reaction of benzil with triphenylphosphorusmethylene

A study of the mechanism of the abnormal claisen rearrangement

A study of the acid catalyzed rearrangement of 4-oxo-3, 3-dimethyl-3, 4-dihydrophenanthrene

A reinvestigation of the Claisen rearrangement of allyl o-tolyl ether

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