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Filtering by: Creator Munson, Mary K. Remove constraint Creator: Munson, Mary K. Advisor Marvell, Elliot N. Remove constraint Advisor: Marvell, Elliot N. Degree Field Chemistry Remove constraint Degree Field: Chemistry

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Thermolysis of cis,cis,trans-1-phenyl-1,3,5-heptatriene

Creator:

Tilton, Mary Lehman

Abstract:

Isomerically pure cis,cis,trans-1-pheny1-1,3,5- heptatriene was prepared and cyclized. Ring closure was followed by a 1,5 hydrogen shift, and the only product observed was 1-phenyl -6-methyl -1,3-cyclohexadiene. Rough first order rate constants for thermolysis and the hydrogen shift were determined. Kinetic estimates indicate that the report of disallowed product in a...

Resource Type:

Masters Thesis

Full Text:

AN ABSTRACT OF THE THESIS OF Mary Lehman Tilton for the degree of Master of Science in Chemistry
Synthesis of some bicyclo[6.1.0] - nonane derivatives

Creator:

Wall, Robert Gene

Abstract:

Bicyclo [6.1.0] non-4-ene was prepared by two routes; (1) reaction of cis-cis-1, 5-cycloöctadiene with methylene iodide and zinc-copper couple, (2) sodium-methanol reduction of 9, 9-dibromobicyclo-[6.1.0] non-4-ene. The bicyclononene was characterized by its infrared spectrum, nuclear magnetic resonance spectrum and common physical properties. The olefin was hydrogenated to bicyclo [6.1.0] -...

Resource Type:

Masters Thesis

Full Text:

Society 84:1935 -1940. 1962. 35 16. Cope, Arthur C. and Mary J. Youngquist. Proximity ef- fects
Kinetic studies of some thermal rearrangements

Creator:

Schatz, Bruce Stewart

Resource Type:

Dissertation

Full Text:

was shown to yield cis -5, 6- dimethyl-1, 3-cyclohexadiene: k = 4. 45 X 10-5 sec-1 at 132', k = 2
Studies on the mechanism of formation of n-phenylpyridinium salts from 1,7-diaza-1,3,5-heptatrienes

Creator:

Shahidi, Iraj Khatib

Resource Type:

Dissertation

Full Text:

kinetics, k =6 x10-6sec-1 at 400 , and can be readily followed by U. V. -vis, spectroscopy. In methanol
The mechanism of the para-Claisen rearrangement

Creator:

Teranishi, Roy, 1922-2000

Resource Type:

Dissertation

Full Text:

_ ,-:, ?/, fgr'/ Typed by Mary Willits TABLE OF CONTENTS Page Introduction. . . . . . . . e . . . . e
Valence tautormerism in cis-1, 2-di-1'-cyclohexen-1'-ylethylene

Creator:

Pippin, Wallace Harold

Resource Type:

Masters Thesis

Full Text:

-phase 23 chromatography (6 ft. type K column at 2000) showed only one peak (apparent reten
Some studies relating to the stereochemistry of the Claisen rearrangement of cis- and trans-α ,γ- dimethylallyl phenyl ethers

Creator:

Ong, Josephine

Resource Type:

Dissertation

Full Text:

k3 and k4 from the following kinetic k1 1 + k 2, and kcis = k3 + k 4' trans- ether cis
Isolation and identification of certain toxic compounds in a fraction of Kraft mill waste

Creator:

Wiman, Robert Edgar, 1933-

Resource Type:

Dissertation

Full Text:

chromatographed on a 6' x %" type "K" column (75 °C flow 43, 15 psi). Four peaks were found (Rt 0.8, 1.4%; 3.2
The retro-ene reaction of 2-vinylcyclohexanols and approaches to the synthesis of botryococcene

Creator:

Rusay, Ronald Joseph

Abstract:

The retro-ene reaction of 2-vinylcyclohexanols occurs readily in the vapor phase at 400-450° producing unsaturated carbonyl compounds in good yields. The starting- materials were prepared in general by the carbenoid addition reaction of ethyl diazoacetate, appropriately substituted cyclohexene, and copper catalyst to produce bicyclic esters which were reduced to the...

Resource Type:

Dissertation

Full Text:

preponderance of the trans material. 38, 39 Scheme 3 k OH 18 H Our isolated product was oxidized to the
Preparation and semihydrogenation of some a, β-acetylenic ketones

Creator:

Churchley, Philip Leslie

Resource Type:

Masters Thesis

Full Text:

(run 3). \r' ,\ I li / (, AFigure I 35 BIBLIOGRAPHY J. Auwers, K. Y. Effects of ring closure

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Academic Affiliation

Chemistry11

Advisor

Marvell, Elliot N.[remove]11

Commencement Year

Commencement Year range begin – Commencement Year range end

Current results range from 1954 to 1982

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Creator

Churchley, Philip Leslie1
Ong, Josephine1
Pippin, Wallace Harold1
Rusay, Ronald Joseph1
Schatz, Bruce Stewart1
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Date

Date range begin – Date range end

Current results range from 1954 to 1981

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1980-19892
1970-19791
1960-19697
1950-19591

Degree Field

Chemistry[remove]11

Degree Level

Doctoral7
Master's4

Degree Name

Doctor of Philosophy (Ph.D.)7
Master of Science (M.S.)4

Language

English [eng]11

Non-Academic Affiliation

Oregon State University. Graduate School11

Peer Reviewed

No11

Resource Type

Dissertation7
Masters Thesis4

Rights Statement

Copyright Not Evaluated11

Subject

Bicyclic compounds1
Chemical reactions1
Claisen condensation1
Claisen rearrangement1
Ethers1
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