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Filtering by: Creator Belcher, Araby R. Advisor Marvell, Elliot N.

Approaches to the synthesis of botryococcene : synthesis of the half molecule

Creator:

Strycker, Arden R.

Resource Type:

Dissertation

Full Text:

the Half Molecule AN ABSTRACT OF THE THESIS OF Arden R. Strycker for the degree of Doctor of
The retro-ene reaction of 2-vinylcyclohexanols and approaches to the synthesis of botryococcene

Creator:

Rusay, Ronald Joseph

Abstract:

The retro-ene reaction of 2-vinylcyclohexanols occurs readily in the vapor phase at 400-450° producing unsaturated carbonyl compounds in good yields. The starting- materials were prepared in general by the carbenoid addition reaction of ethyl diazoacetate, appropriately substituted cyclohexene, and copper catalyst to produce bicyclic esters which were reduced to the...

Resource Type:

Dissertation

Full Text:

- ably substituted starting materials. Scheme 1 R OH A 0 R' The retro-ene process was to be applied
Preparation of propylcyclohexanes with functions on the 4 and 3' positions

Creator:

Rowell, Charles Frederick

Abstract:

The preparation of 4-(3-hydroxypropyl) cyclohexanone and of 4-(3-hydroxypropyl) cyclohexene and a number of their derivatives as potential precursors of asymmetrically substituted bicyclo [3, 3, 1] nonanes is described. The ketone, 4-(3-hydroxypropyl) cyclohexanone, was prepared from p-allylanisole by three different routes. Common to each route was an initial hydroboration-oxidation followed by...

Resource Type:

Dissertation

Full Text:

,' .r'/',:.:i-;' Title 4 and Preparation of Propylcyclohexanones with Fr:nctions on the 3r positions