High-potential molecules derived from biomass sources may suitably replace or supplement traditional nonrenewable hydrocarbon fuels to reduce pollution and fuel processing costs. Due to expensive and time-consuming property testing, models that predict key properties from optical data would initially vet potential additives before investment and bench-scale testing. Attenuated Total Reflection...
Smoldering combustion in wildland fires is a critical phenomenon that needs in-depth study because it can initiate with weaker ignition sources, can persist for long periods, is difficult to suppress, and can transit to flaming combustion. Cellulose, hemicellulose, and lignin are the major organic constituents within biomass, in varying proportions...
The aerospace industry uses chemical kinetic models when designing propulsion systems to acquire specific details about the rate of chemical reactions, heat release, and combustion stability. These models, however, are too large and stiff to be useful as they can take weeks to run computations on. The pyMARS python package...
Small hydrocarbon particles such as soot and soot precursors pose a serious threat to human health and Earth's climate. Understanding the mechanisms by which soot particles form and grow is the first step to reducing the prevalence of these particles. Computational simulations are used to investigate combusting systems which are...
Gasoline direct injection engines, with downsized boosted technology, present a promising option for enhancing power density and reducing fuel consumption for next-generation engine designs to meet stringent fuel economy and emission standards. However, these developments in the low-speed and high-load operating regime are challenged by the occurrence of a new...
Combustion emissions produced from burning real transportation fuels have many environmental impacts. However, detailed chemistry across multiple phases, time scales, and thermodynamic conditions make predicting combustion emissions challenging. Detailed modeling of the gas phase alone is prohibitively expensive, due to the large size and stiffness of the kinetic models. The...
Implementing multicomponent diffusion in numerical combustion studies is computationally expensive due to the challenges involved in computing diffusion coefficients. As a result, mixture-averaged diffusion treatments or simpler methods are used to avoid these costs. However, the accuracy and appropriateness of the mixture-averaged diffusion model has not been verified for three-dimensional...
Due to global warming wildland fires are increasing in frequency and severity. In the case of wildland fires, the major modes of combustion occur include smoldering combustion and flaming combustion. Smoldering combustion occurs most commonly in porous fuels like peat, forest duff, and woody fuels, which are available in abundance...