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Filtering by: Creator Hofmann, Clark Remove constraint Creator: Hofmann, Clark Contributor advisor sim Gable, Kevin P. Remove constraint Contributor advisor sim: Gable, Kevin P.

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  • Mechanistic studies on Re(V) mediated C-O bond transformations

    Creator:
    Zhuravlev, Fedor
    Abstract:
    In situ, reduction of Cp*ReO₃ by PPh₃ to form (Cp*ReO)₂(μ-O)₂ allows catalytic deoxygenation of epoxides, however, conproportionation between Reⱽ and Reⱽᴵᴵ species to form clusters of ((Cp*Re)₃(μ-O)₆}²⁺(ReO₄⁻)2 and new compound {(Cp*Re)₃(μ²-O)₃(μ³-O⁾³ReO₃}⁺(ReO₄⁻) leads to removal of rhenium from the catalytic cycle and loss of activity, The epoxide deoxygenation mediated by (Cp*ReO)₂(μ-O)₂...
    Resource Type:
    Dissertation