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Filtering by: Contributor advisor sim Krueger, James H. Committee Member Tarter, N. L.

Synthesis and oxidation of metal-thiolate compounds which mimic the active site function of thiolate dioxygenase enzymes

Creator:

Schussel, Leonard J.

Abstract:

Part I describes the synthesis of bis(fac-S)((tris)2-aminoethanethiolatoiron( III))iron(III) chloride. The compound was first discovered during an attempt to prepare a ternary complex of iron, thiolate and pi-acid ligand. The compound is a reasonably air-stable iron(III)-thiolate that contains a linear tri-iron cluster with each iron bridged to the adjacent iron by...

Resource Type:

Dissertation