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Filtering by: Contributor advisor sim Krueger, James H. Creator Herting, Daniel L. Peer Reviewed No

Reactions and stereochemistry of thiolato and sulfenato cobalt (III) complexes

Creator:

Herting, Daniel L.

Abstract:

This thesis describes a study of the synthesis, stereochemistry, and reactivity of cobalt(III) cysteinato (CyS) and related thiolato complexes. The preparation of [Co(en)₂CyS]⁺ resulted in a product solution containing a mixture of diastereomers in the ratio 2.3:1 (Δ:A). The isomers were separated by ion exchange chromatography, and their absolute configurations...

Resource Type:

Dissertation