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Filtering by: Committee Member Kopperman, Paul E. Remove constraint Committee Member: Kopperman, Paul E. Committee Member Blakemore, Paul R. Remove constraint Committee Member: Blakemore, Paul R.

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  • The development of aminal radicals for the synthesis of nitrogen-rich natural products

    Creator:
    Schiedler, David A.
    Abstract:
    Organic compounds which contain one or more nitrogen atoms are especially important as they are disproportionately represented among biologically active molecules. As a result, significant effort has been focused on the development of methods for the synthesis of nitrogenous molecules. We identified the aminal as an under-explored functional group. Despite...
    Resource Type:
    Dissertation
    Full Text:
    . 1996, 118, 9200–9201. 7 Walling, C.; Huyser, E. S. Org. Reactions 1963, 13, 91. 8 For selected

  • Studies towards the total synthesis of (-)-kendomycin

    Creator:
    Smits, Helmars
    Abstract:
    Studies towards the total synthesis of (−)-kendomycin (1), a bacterial metabolite with a unique molecular architecture and pronounced biological activity, are described. These studies resulted in the synthesis of advanced intermediate 208, containing all of the carbon atoms of 1. A Dötz annulation between alkyne 122 and novel chromium carbenoid...
    Resource Type:
    Dissertation
    Full Text:
    committee members, Professor David Horne, Professor Paul Blakemore, Professor Max Deinzer and Professor