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Filtering by: Creator Ruehl-Fehlert%2C Christine Remove constraint Creator: Ruehl-Fehlert%2C Christine Committee Member Blakemore, Paul R. Remove constraint Committee Member: Blakemore, Paul R.

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  • Expanding the scope of a Diels-Alder approach to biaryl synthesis

    Creator:
    Schwartz, Johanna Perkins
    Abstract:
    A Diels-Alder approach to biaryls (DAB) has been applied towards the synthesis of highly substituted, programmable biaryl templates. Tri- and tetra-ortho-substituted biaryls can be produced in just three to four steps from commercially available materials utilizing the Diels-Alder [4+2] cycloaddition. The methods described herein will illustrate the ability of mono...
    Resource Type:
    Dissertation
    Full Text:
    . William Martin for his continued friendship and advice, Emile Firpo and Dr. Christine Pastorek for their

  • Cis-2,5-diaminobicyclo[2.2.2]octane : a novel C₂-symmetric scaffold for asymmetric catalysis

    Creator:
    Shaw, Subrata
    Abstract:
    This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
    Resource Type:
    Dissertation
    Full Text:
    Firpo, Dr. John Loeser and Dr. Christine Pastorek for having me in their teaching lab with such