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Filtering by: Creator Stockberger, Roxy A. Remove constraint Creator: Stockberger, Roxy A. Committee Member DeKock, Carroll Remove constraint Committee Member: DeKock, Carroll

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  • Studies on the biosynthesis of the streptolidine moiety of streptothricin F

    Creator:
    Wityak, John
    Abstract:
    The loss of all deuterium labels from previous feedings of [2-²H]-, [3,3-²H₂]-, and [2,3,3-²H₃]arginines had indicated the possible intermediacy of β-hydroxy- and β-ketoarginine (30 and 31, respectively) in the biosynthesis of the streptolidine portion of streptothricin F (la). In order to confirm or refute this evidence, D,L-[2,3,3,5,5-²H₅]- arginine (32) was...
    Resource Type:
    Dissertation
    Full Text:
    -2H 5]- arginine (3 2) was synthesized via a 4 step route from diethyl acetamidomalonate (90). The