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Filtering by: DOI 10.1007/s12393-014-9075-x Remove constraint DOI: 10.1007/s12393-014-9075-x Committee Member Lerner, Michael M. Remove constraint Committee Member: Lerner, Michael M. Degree Field Chemistry Remove constraint Degree Field: Chemistry

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  • The Role of Materials Chemistry in Designing Advanced Color Inorganic Pigments

    Creator:
    Medina, Elena A.
    Abstract:
    The results of the research presented in this work are related to synthesis and investigations of novel color inorganic pigments having various structures and shades. Inorganic pigments play a major role in contemporary life. They are used in paints, rubber, plastic, cosmetics etc. Searching for new, stable, environmentally benign and...
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    Dissertation
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    studied using various methods and techniques including powder X-ray (XRD) and neutron diffraction

  • Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

    Creator:
    Jieratum, Vorranutch
    Abstract:
    The materials Fe₂(Si,Ge)(S,Se)₄, Cu₃PS[subscript 4-x]Se[subscript x] (0 ≤ x ≤ 4), and Cu₃PxAs[subscript 1-x]S₄ (0 ≤ x ≤ 1) have been synthesized and studied as new earth-abundant absorbers for single and multijunction photovoltaic cells as well as solar fuel generation. The synthesis, single-crystal growth, and optical and electrical properties of...
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    Dissertation
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    : ____________________________________________________ Douglas A. Keszler The materials Fe2(Si,Ge)(S,Se)4, Cu3PS4-xSex (0 ≤ x ≤ 4), and Cu3PxAs1

  • Structure-property relationships in oxides containing tellurium

    Creator:
    Siritanon, Theeranun
    Abstract:
    Oxides of post-transition metals often show unique structures and properties due to the presence of lone pair electrons and the diffused s orbitals. The present work focuses on synthesis and characterizations of oxides containing Te, a heavy post transition metal. New series of pyrochlore oxides of the formula Cs(M,Te)₂O₆ (M...
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    Dissertation
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    with CsTe2O6-x where x = 0, 0.15, 0.25, 1.5 have been investigated. On heating at slightly above

  • Polyoxoniobates: fundamental solubility trend and their application in solution and on the surface of thin films

    Creator:
    Rahman, Tasnim
    Abstract:
    Polyoxometalates (POMs) are anions consisting of three or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked together by a shared oxygen bond to form a 3D framework. Polyoxometalates (POMs) are a rapidly growing class of metal oxo clusters with a wide range...
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    Dissertation
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    protonation sites available in the cluster structures. {Nb24O72Hx} (24-x)-, {Ti2Nb8O28} 8- and {TiNb9O28} 7

  • The Local Structure of Functional Electroceramics

    Creator:
    Culbertson, Charles M.
    Abstract:
    This work investigates the relationship between the local structure and physical properties of a set of classical (MgTiO3, CaTiO3, SrTiO3, and BaTiO3) and complex ((1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3[BZT-BCT], Na0.5Bi0.5TiO3 [NBT]) perovskite electroceramics. The materials in this work were synthesized via standard solid state ceramic synthesis, the structure was investigated through a number of...
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    Dissertation
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    -x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3[BZT-BCT], Na0.5Bi0.5TiO3 [NBT]) perovskite electroceramics

  • Exploratory Studies Within the Exotic Lyonsite Structure

    Creator:
    Tang, Joseph N.
    Abstract:
    Structure-property relationships have always underpinned the field of solid state chemistry; dependable structural descriptions are integral to understanding and controlling the physical properties of inorganic compounds old and new. While a handful of crystal structures are celebrated for their versatility, flexibility, and functionality, the existence of more exotic structures is...
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    Dissertation
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    samples were annealed between 700 and 1000 °C, resulting in green-colored pastilles. Powder X-ray

  • Synthesis and investigation of layered oxides with honeycomb ordering

    Creator:
    Schmidt, Whitney L.
    Abstract:
    Synthesis and discovery lies at the core of every field in chemistry. The investigation of the structure-property relationships in compounds known or new is the fundamental purpose of solid state chemistry. Mixing related solid state compounds to form solid solutions can lead to exciting new and/or unexpected properties. Layered compounds...
    Resource Type:
    Dissertation
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    -sharing octahedra. X-ray diffraction verified lattice parameter trends based on the ionic radii of the

  • Copper and iron chalcogenides for efficient solar absorption

    Creator:
    Platt, Heather A. S.
    Abstract:
    This dissertation outlines two approaches for improving the efficiency and reducing the cost of photovoltaic energy generation. First, the structures of known binary copper and iron compounds are used to choose the promising compositions Fe₂XS₄ (X = Si, Ge), Cu₃TaQ₄ (Q = Se, Te), and BaCuQ'F (Q' = S, Se,...
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    Dissertation
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    choose the promising compositions Fe2XS4 (X = Si, Ge), Cu3TaQ4 (Q = Se, Te), and BaCuQ’F (Q’ = S, Se, Te

  • High quantum-yield phosphors via quantum splitting and upconversion

    Creator:
    Jeong, Joayoung
    Abstract:
    The Gd3+ ion has been used to induce quantum splitting in luminescent materials by using cross-relaxation energy transfer (CRET). In Nd:LiGdF4, quantum splitting results from a two-step CRET between Gd3+ and Nd3+, first involving a transition 6G→6I on Gd3+ and an excitation within the 4f3 configuration of Nd3+ followed by...
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    Dissertation
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    material GdZrF7 were grown, and its structure was established via single-crystal X-ray diffraction

  • New luminescent materials and high-performance solution-processed oxide thin films

    Creator:
    Jiang, Kai
    Abstract:
    Crystals of an incongruent-melting compound, Ba₃MgSi₂O₈, were grown by the flux method and its structure was determined by single crystal X-ray diffraction methods. Ba₃MgSi₂O₈ crystallizes in trigonal space group P-3[bar]m1 with a = 5.6123(3) Å, c = 7.2667(9) Å and Z = 1. Eu²⁺ ions prefer one crystallographic Ba site...
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    Dissertation
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    crystal X-ray diffraction methods. Ba3MgSi2O8 crystallizes in trigonal space group P 3 m1 with a