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Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

Creator:: Jieratum, Vorranutch
Abstract:: The materials Fe₂(Si,Ge)(S,Se)₄, Cu₃PS[subscript 4-x]Se[subscript x] (0 ≤ x ≤ 4), and Cu₃PxAs[subscript 1-x]S₄ (0 ≤ x ≤ 1) have been synthesized and studied as new earth-abundant absorbers for single and multijunction photovoltaic cells as well as solar fuel generation. The synthesis, single-crystal growth, and optical and electrical properties of...
Resource Type:: Dissertation
Full Text:: effective ionic radii (Å) [8] for coordination number (CN) = 4 and 6 of Cu + , P 5+ , As 5+ and Sb 5

Structure-property relationships in oxides containing tellurium

Creator:: Siritanon, Theeranun
Abstract:: Oxides of post-transition metals often show unique structures and properties due to the presence of lone pair electrons and the diffused s orbitals. The present work focuses on synthesis and characterizations of oxides containing Te, a heavy post transition metal. New series of pyrochlore oxides of the formula Cs(M,Te)₂O₆ (M...
Resource Type:: Dissertation
Full Text:: 600ºC, CsTe2O6 loses oxygen resulting in cubic structure with disordered Te 4+/ Te 6+ and oxygen

Fundamental Studies of the Structure-Property Correlations of Na-ion and K-ion Storage in Non-Graphitic Carbon

Creator:: Li, Zhifei
Abstract:: Grid-scale energy storage systems are urgently needed to increase the flexibility and rigidity of the grid for modern society and take full advantage of the renewable green energy resources such as solar energy and wind energy. Na-ion batteries (NIBs) and K-ion batteries (KIBs) have been emerged as one of the...
Resource Type:: Dissertation
Full Text:: treatment, i.e., for 6 seconds, the reversible capacity of the hard carbon was increased from 204 to 308

Polyoxoniobates: fundamental solubility trend and their application in solution and on the surface of thin films

Creator:: Rahman, Tasnim
Abstract:: Polyoxometalates (POMs) are anions consisting of three or more early transition metals ™ (Gr V and VI) oxoanions (in their highest oxidation state) linked together by a shared oxygen bond to form a 3D framework. Polyoxometalates (POMs) are a rapidly growing class of metal oxo clusters with a wide range...
Resource Type:: Dissertation
Full Text:: using {Nb6O19} 8-, {Nb10O27} 6-, { Nb24O72Hx} (24-x)- and {Zr4(OH)8(H2O)16Cl6 2+}metal oxo clusters

The Local Structure of Functional Electroceramics

Creator:: Culbertson, Charles M.
Abstract:: This work investigates the relationship between the local structure and physical properties of a set of classical (MgTiO3, CaTiO3, SrTiO3, and BaTiO3) and complex ((1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3[BZT-BCT], Na0.5Bi0.5TiO3 [NBT]) perovskite electroceramics. The materials in this work were synthesized via standard solid state ceramic synthesis, the structure was investigated through a number of...
Resource Type:: Dissertation
Full Text:: structure was investigated through a number of different scattering methods to probe different aspects of

A unified approach for the total synthesis of C₁₀-functionalyzed Lycopodium alkaloids

Creator:: Saha, Mrinmoy
Abstract:: Lycopodium alkaloids have shown widespread and noteworthy biological activity, consisting of over 250 known natural products. Moreover, their structural complexity and diversity have attracted considerable attention from numerous laboratories including our own. Recently, we have developed a unified approach that would provides access to numerous, previously unprepared C₁₀-functionalized lycopodium alkaloids....
Resource Type:: Dissertation
Full Text:: ....................................................................................................... 127 Chapter 6: Studies Towards Eastern Half of Himeradine A

Phosphor development : synthesis, characterization, and chromatic control

Creator:: Li, Dong
Resource Type:: Dissertation
Full Text:: of Philosophy in Chemistry presented on April 6, 1999. Title: Phos hor Develo ment: S nthesis

Synthesis and study of oxides and chalcogenides : thin films and crystals

Creator:: Park, Sangmoon
Abstract:: Several types of solid-state inorganic materials are prepared and characterized. By using the SILAR (Successive Ionic Layer Adsorption and Reaction) deposition method in conjunction with hydrothermal dehydration both low-temperature deposition and crystallization of oxide thin films are achieved. Various aspects of new transparent p-type materials are studied by examining both...
Resource Type:: Dissertation
Full Text:: , Hiroshi Yanagi, and Dr. Tate Janet collaborated in Chapter 6. Dr. Alex Yokochi assisted the structural

Computational Investigation and Prediction of Mechanisms and Stereocontrol in Complex Organic Reactions

Creator:: Pattawong, Ommidala
Abstract:: Complex organic transformations, such as the addition of pyrrole to ketene using planar chiral organocatalyst (*PPY), the four-component anhydride- Manniach reactions, and the site-selective desymmetrization of meso-1,2-diol, are remarkable synthetic reactions that provide high yield and high selectivity. However, the exact mechanism and origins of stereocontrol for theses synthetic organic...
Resource Type:: Dissertation
Full Text:: preparation and review of this manuscript. Chapter 6. Paul Ha-Yeon Cheong contributed in part to the

The Role of Materials Chemistry in Designing Advanced Color Inorganic Pigments

Creator:: Medina, Elena A.
Abstract:: The results of the research presented in this work are related to synthesis and investigations of novel color inorganic pigments having various structures and shades. Inorganic pigments play a major role in contemporary life. They are used in paints, rubber, plastic, cosmetics etc. Searching for new, stable, environmentally benign and...
Resource Type:: Dissertation
Full Text:: at NIST. Chapter 6: Dr. Jun Li assisted in the data analysis and review of the manuscript on which

ScholarsArchive@OSU

Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF7 : a new upconversion host, Iron and copper chalcogenides : photovoltaic absorber candidates and YZrF₇ : a new upconversion host

Structure-property relationships in oxides containing tellurium

Fundamental Studies of the Structure-Property Correlations of Na-ion and K-ion Storage in Non-Graphitic Carbon

Polyoxoniobates: fundamental solubility trend and their application in solution and on the surface of thin films

The Local Structure of Functional Electroceramics

A unified approach for the total synthesis of C₁₀-functionalyzed Lycopodium alkaloids

Phosphor development : synthesis, characterization, and chromatic control

Synthesis and study of oxides and chalcogenides : thin films and crystals

Computational Investigation and Prediction of Mechanisms and Stereocontrol in Complex Organic Reactions

The Role of Materials Chemistry in Designing Advanced Color Inorganic Pigments

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