Over the last two decades, urban stormwater management has grown to include green infrastructure, such as bioswales. These systems were primarily designed to mitigate hydraulic peaking during rainstorms but were also found to remove particulate and dissolved contaminants. However, little is known about the fate of these particulate contaminants after...
Best Management Practices (BMP) are widely used as a method for stormwater volume control in urban areas to prevent an overload of water on receiving water bodies and treatment facilities. BMPs ability to treat stormwater has gone under critical review in the last few decades, and their performance varies both...
Lead (Pb), copper (Cu), and zinc (Zn) are known to have detrimental effects on aquatic and terrestrial ecosystems, and to human health both in rural and urban areas. Heavy metal contamination enters stormwater by atmospheric deposition and by the collection of surface particles during overland flow. Stormwater runoff in urban...
Nanoparticles (NPs), defined by their size (1-100 nm), are increasingly incorporated into commercial and industrial products due to their high surface area and unique properties. They can be designed for specific applications by manipulating composition, size, shape, and surface functionalization. As NP production and complexity increases, there is a need...
Passage of blood through a sorbent device for removal of bacteria and endotoxin by specific binding with immobilized, membrane-active, bactericidal peptides holds promise for treating severe blood infections. Peptide insertion in the target membrane and stable binding is desirable, while membrane disruption and release of degradation products to the circulating...
Numerous studies have shown that some nanomaterials are highly toxic to aquatic organisms and can potentially disrupt overall community health; however, current methods to evaluate the nanomaterials environmental impacts rarely consider the environmental realism or provide sufficient detail on the impact at the community level. Here we demonstrate three approaches...
Complex organic transformations, such as the addition of pyrrole to ketene using planar chiral organocatalyst (*PPY), the four-component anhydride- Manniach reactions, and the site-selective desymmetrization of meso-1,2-diol, are remarkable synthetic reactions that provide high yield and high selectivity. However, the exact mechanism and origins of stereocontrol for theses synthetic organic...
Nanomaterials are expected to enable significant advances in several technological fields in coming years. Among them, electronics has emerged as one of the most likely benefactors from the ability to control matter on the nanometer-scale. For many electronic devices synthesized nanomaterials must be integrated into thin film structures. Vapor-based deposition...
Silver nanoparticles are increasingly being incorporated into consumer products due to their broad-spectrum antimicrobial properties. The resulting influx of silver nanoparticles into wastewater may pose a threat to bacteria involved in biological wastewater treatment. Ammonia-oxidizing bacteria, which convert ammonia to nitrite in the first step of nitrification, are highly sensitive...
This work is an attempt to develop a simple physical description for the initial
interactions between a bacterial cell and a substrate surface. This is done by
adopting a view that regards bacterial surface biomolecules not as secondary and
add-on contributors to the potential energy function that characterizes the
overall...