This thesis deals with applications of uniaxial anisotropic crystals for microcavity resonators with partially chaotic underlying ray dynamics. We develop an implementation of the scattering matrix formalism, and relate the eigenvalues and eigenvectors of the scattering matrix to the field distribution of inside the system. Using the developed technique, we...
The stereospecific reagent-controlled homologation (StReCH) of boronic esters with enantioenriched carbenoid species generated in situ by the addition of organolithium initiators to stereodefined α-chloroalkyl aryl sulfoxides was previously reported. The reaction of an organolithium with an α-chloroalkyl aryl sulfoxide ostensibly generates an α-chloroalkyllithium via sulfoxide-lithium exchange; however, the true nature...
In previous work (Blakemore et al. Org. Lett. 2005, 7, 4721; Heterocycles 2006, 70, 609), successful elaborations of the lupine alkaloids (±)-α-isosparteine (dl-2) and (±)-β-isosparteine (dl-3) were realized from a common tetraoxobispidine precursor, 3,7-diallyl -2,4,6,8-tetraoxo-3,7-diazabicyclo[3.3.1]nonane (93). Herein, the tetraoxobispidine approach to lupine alkaloids was extended to a total synthesis of...
Xanthohumol [XN, (E)-6´-methoxy-3´-(3-methylbuten-2-yl)-2´,4´,4´´-trihydroxychalcone], the principal prenylated chalcone from hops, and its 2,3-dihydro- (DXN) and O6-desmethyl-2,3-dihydro- (DDXN) congeners, are of potential utility for the amelioration of metabolic syndrome; however, their complex bioactivity profiles cannot be properly studied and understood without access to appropriately produced synthetic materials.
In the first part of...
Ab initio calculations using the B3LYP and CCSD(T) methods were employed in this work to explore the most stable structure of the intriguing compound Be(BH₄)₂, for which as many as seven different structures have been proposed in the literature. Use of the B3LYP density functional method with several large basis...
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3.4: Theoretical rovibrational parametersa (cm-1) of the fundamental levels of D3d form
With increasing transistor operating frequencies, interconnects and passive devices are becoming performance limiters in integrated circuit (IC) designs. To combat this, the interconnect layers above the active silicon are trending toward low-κ dielectrics and Cu metallization. The use of these new materials has popularized chemical mechanical polishing (CMP) to planarize...
Thin-film transistors (TFTs) are primarily used as a switching element in liquid crystal
displays. Currently, amorphous silicon is the dominant TFT technology for displays, but
higher performance TFTs will become necessary to enable ultra-definition resolution
high-frequency large-area displays. Amorphous zinc tin oxide (ZTO) TFTs were
fabricated by RF magnetron sputter...
Steady flow fields and flow-induced wall stresses have been evaluated by experimental measurements and computational fluid dynamics (CFD) analysis in a series of patient-specific abdominal aortic aneurysm (AAA) models, over a range of Reynolds numbers (Re) from 125 to 3000 (500 to 3000 for CFD). Experimental methods used particle image...