Index Catalog // ScholarsArchive@OSU

Total synthesis of sparteine alkaloids from a common tetraoxobispidine intermediate

Creator:: Melbardis, John
Abstract:: In previous work (Blakemore et al. Org. Lett. 2005, 7, 4721; Heterocycles 2006, 70, 609), successful elaborations of the lupine alkaloids (±)-α-isosparteine (dl-2) and (±)-β-isosparteine (dl-3) were realized from a common tetraoxobispidine precursor, 3,7-diallyl -2,4,6,8-tetraoxo-3,7-diazabicyclo[3.3.1]nonane (93). Herein, the tetraoxobispidine approach to lupine alkaloids was extended to a total synthesis of...
Resource Type:: Masters Thesis
Full Text:: Tetraoxobispidine Intermediate Abstract approved: Paul R. Blakemore In previous work (Blakemore et al

Total Synthesis of Isotopologues of Xanthohumol and its Congeners for Biological Studies

Creator:: Plagmann, Layhna S.
Abstract:: Xanthohumol [XN, (E)-6´-methoxy-3´-(3-methylbuten-2-yl)-2´,4´,4´´-trihydroxychalcone], the principal prenylated chalcone from hops, and its 2,3-dihydro- (DXN) and O6-desmethyl-2,3-dihydro- (DDXN) congeners, are of potential utility for the amelioration of metabolic syndrome; however, their complex bioactivity profiles cannot be properly studied and understood without access to appropriately produced synthetic materials. In the first part of...
Resource Type:: Masters Thesis
Full Text:: Isotopologues of Xanthohumol and its Congeners for Biological Studies Abstract approved: Paul

Synthesis and catalytic applications of derivatives of 7,7'-dihydroxy-8,8'-biquinolyl (azaBINOL)

Creator:: Wang, Chao
Abstract:: The synthesis of axially chiral polyfunctional derivatives of 8,8'-biquinolyl was explored and the catalytic action of appropriate derivative types investigated in three separate processes: (1) the silylcyanation of carbonyl groups and imines, (2) alkylation of a glycine Schiff-base via phase transfer-catalysis, and (3) direct amide bond formation from simple amines...
Resource Type:: Dissertation
Full Text:: : Paul R. Blakemore The synthesis of axially chiral polyfunctional derivatives of 8,8´-biquinolyl

Analysis of the mechanism of sulfoxide-lithium exchange and the reactive intermediate in stereospecific reagent-controlled homologation (StReCH)

Creator:: Hoyt, Amanda
Abstract:: The stereospecific reagent-controlled homologation (StReCH) of boronic esters with enantioenriched carbenoid species generated in situ by the addition of organolithium initiators to stereodefined α-chloroalkyl aryl sulfoxides was previously reported. The reaction of an organolithium with an α-chloroalkyl aryl sulfoxide ostensibly generates an α-chloroalkyllithium via sulfoxide-lithium exchange; however, the true nature...
Resource Type:: Masters Thesis
Full Text:: : Paul R. Blakemore The stereospecific reagent-controlled homologation (StReCH) of boronic esters

Expediting the Generation and Analysis of Amorphous Oxide Computational Models: Modeling Complex Systems Swiftly

Creator:: Buchanan, Jacob C.
Abstract:: In this dissertation, the process of computational modeling of amorphous oxide materials is studied. Amorphous oxides have random atomic arrangements with no long-range structural order which makes it difficult to study structure-property relationships. Despite the difficulties, amorphous oxides have great uses as semiconductors and dielectrics in thin-film transistors. The ability...
Resource Type:: Dissertation
Full Text:: : ___________________________________________________ Paul Ha-Yeon Cheong In this dissertation, the process of computational modeling of

Terahertz transmission & spectroscopy of vertically grown multi-walled carbon nanotube forests

Creator:: Maizy, Louis
Abstract:: In this thesis, I present studies in the field of terahertz [THz] spectroscopy. It covers both the generation and detection of ultra-fast broadband THz pulses, as well as the transmission properties of vertically grown multi-walled carbon nanotube forests [MWCNTs]. We have found that these vertically grown MWCNTs respond strongly to...
Resource Type:: Masters Thesis
Full Text:: . Paul, N. A. Kuhta, J. L. Tomaino, A. D. Jameson, L. P. Maizy, T. Sharf, N. L. Ru- pesinghe, K. B. K

Scanning photocurrent microscopy study of photovoltaic and thermoelectric effects in individual single-walled carbon nanotubes

Creator:: DeBorde, Tristan
Abstract:: Carbon Nanotubes are a unique family of nanostructures that have shown remarkable promise for mechanical, electrical, and optical applications. Fundamentally similar to the earlier discovered Buckminsterfullerene (C₆₀), carbon nanotubes are hollow cylinders formed from a single sheet of carbon atoms. The research presented in this dissertation investigates several carbon nanotube...
Resource Type:: Dissertation
Full Text:: . 12 1.5 References 1 Wilder, J. W. G., Venema, L. C., Rinzler, A. G., Smalley, R. E. & Dekker

Generating and using terahertz radiation to explore carrier dynamics of semiconductor and metal nanostructures

Creator:: Jameson, Andrew D.
Abstract:: In this thesis, I present studies in the field of terahertz (THz) spectroscopy. These studies are divided into three areas: Development of a narrowband THz source, the study of carrier transport in metal thin films, and the exploration of coherent dynamics of quasi-particles in semiconductor nanostructures with both broadband and...
Resource Type:: Dissertation
Full Text:: Maxwell’s equations [37]: t B E    (2.1.1) J t E B 000      (2.1.2) 0

Influence of processing parameters on diffusion of divalent nickel in wet silica sol-gel monoliths

Creator:: Dickson, David J.
Abstract:: The diffusion of divalent nickel (Ni²⁺) from wet silica gels was investigated. Silica gel is gaining interest as an encapsulation matrix for biological components. The transport of biologically relevant species within the gel is determined by the structural characteristics of the gel, which are in turn governed by synthesis parameters....
Resource Type:: Masters Thesis
Full Text:: AN ABSTRACT OF THE THESIS OF David J. Dickson for

Per- and Polyfluoroalkyl Substances (PFAS) in Environmental Air-Water Matrices and Light Non-Aqueous Phase Liquids (LNAPL)

Creator:: Schwichtenberg, Trever J.
Abstract:: The presence of per- and polyfluoroalkyl substances (PFAS), organic contaminants first synthesized in the 1940s, has been reported worldwide in a variety of environmental matrices and ultimately in biological systems including humans. Ongoing research into PFAS has included identifying novel PFAS, assessing their fate and transport in the environment, and...
Resource Type:: Dissertation
Full Text:: . Second ed.; Marcel Dekker, Inc.: New York, 2001. 2. Krafft, M. P.; Riess, J. G., Selected

ScholarsArchive@OSU

Total synthesis of sparteine alkaloids from a common tetraoxobispidine intermediate

Total Synthesis of Isotopologues of Xanthohumol and its Congeners for Biological Studies

Synthesis and catalytic applications of derivatives of 7,7'-dihydroxy-8,8'-biquinolyl (azaBINOL)

Analysis of the mechanism of sulfoxide-lithium exchange and the reactive intermediate in stereospecific reagent-controlled homologation (StReCH)

Expediting the Generation and Analysis of Amorphous Oxide Computational Models: Modeling Complex Systems Swiftly

Terahertz transmission & spectroscopy of vertically grown multi-walled carbon nanotube forests

Scanning photocurrent microscopy study of photovoltaic and thermoelectric effects in individual single-walled carbon nanotubes

Generating and using terahertz radiation to explore carrier dynamics of semiconductor and metal nanostructures

Influence of processing parameters on diffusion of divalent nickel in wet silica sol-gel monoliths

Per- and Polyfluoroalkyl Substances (PFAS) in Environmental Air-Water Matrices and Light Non-Aqueous Phase Liquids (LNAPL)

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