Index Catalog // ScholarsArchive@OSU

Analysis of the mechanism of sulfoxide-lithium exchange and the reactive intermediate in stereospecific reagent-controlled homologation (StReCH)

Creator:: Hoyt, Amanda
Abstract:: The stereospecific reagent-controlled homologation (StReCH) of boronic esters with enantioenriched carbenoid species generated in situ by the addition of organolithium initiators to stereodefined α-chloroalkyl aryl sulfoxides was previously reported. The reaction of an organolithium with an α-chloroalkyl aryl sulfoxide ostensibly generates an α-chloroalkyllithium via sulfoxide-lithium exchange; however, the true nature...
Resource Type:: Masters Thesis
Full Text:: = 1.11 g/mL, 30% w/w in H2O, MW = 34.01 g/mol, 147 mmol). The resulting mixture was allowed to warm to

Total Synthesis of Isotopologues of Xanthohumol and its Congeners for Biological Studies

Creator:: Plagmann, Layhna S.
Abstract:: Xanthohumol [XN, (E)-6´-methoxy-3´-(3-methylbuten-2-yl)-2´,4´,4´´-trihydroxychalcone], the principal prenylated chalcone from hops, and its 2,3-dihydro- (DXN) and O6-desmethyl-2,3-dihydro- (DDXN) congeners, are of potential utility for the amelioration of metabolic syndrome; however, their complex bioactivity profiles cannot be properly studied and understood without access to appropriately produced synthetic materials. In the first part of...
Resource Type:: Masters Thesis

Synthesis and catalytic applications of derivatives of 7,7'-dihydroxy-8,8'-biquinolyl (azaBINOL)

Creator:: Wang, Chao
Abstract:: The synthesis of axially chiral polyfunctional derivatives of 8,8'-biquinolyl was explored and the catalytic action of appropriate derivative types investigated in three separate processes: (1) the silylcyanation of carbonyl groups and imines, (2) alkylation of a glycine Schiff-base via phase transfer-catalysis, and (3) direct amide bond formation from simple amines...
Resource Type:: Dissertation
Full Text:: . Secondly, I would like to offer my thanks to my committee members Prof. Rich Carter, Prof. Kevin Gable

Cis-2,5-diaminobicyclo[2.2.2]octane : a novel C₂-symmetric scaffold for asymmetric catalysis

Creator:: Shaw, Subrata
Abstract:: This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
Resource Type:: Dissertation
Full Text:: obliged to Professor Rich G. Carter, Paul R. Blakemore and Kevin P Gable from the Department of Chemistry

Electronic and Optical Properties of Defects in Amorphous Oxide and Transition Metal Dichalcogenide Semiconductors

Creator:: Vogt, Kyle
Abstract:: The optical and electronic properties of amorphous oxide thin films depend crucially on chemical composition, and deposition process variations which give rise to sub-gap defect states. Consequently, there is a need for a reliable, high-throughput method to extract sub-gap defect densities of states in amorphous oxide thin films. We present...
Resource Type:: Dissertation
Full Text:: Semiconductors Abstract approved: __________________________________________________ Matthew W. Graham

Total synthesis of sparteine alkaloids from a common tetraoxobispidine intermediate

Creator:: Melbardis, John
Abstract:: In previous work (Blakemore et al. Org. Lett. 2005, 7, 4721; Heterocycles 2006, 70, 609), successful elaborations of the lupine alkaloids (±)-α-isosparteine (dl-2) and (±)-β-isosparteine (dl-3) were realized from a common tetraoxobispidine precursor, 3,7-diallyl -2,4,6,8-tetraoxo-3,7-diazabicyclo[3.3.1]nonane (93). Herein, the tetraoxobispidine approach to lupine alkaloids was extended to a total synthesis of...
Resource Type:: Masters Thesis

Synthesis and Analysis of Heterostructural Semiconductor Alloy Sn1-xCaxCh (Ch=S, Se) and Nitrides Zn1-xWxN and Zn1-x(W1-yMoy)xN

Creator:: Matthews, Bethany E.
Abstract:: This work explores the synthesis and characterization of the metastable alloys Sn1-xCaxCh (Ch= S, Se) and nitride compounds Zn-W-Mo-N, which have recently been predicted by theorists. Single phase thin films of Sn1-xCaxS are prepared by pulsed laser deposition and radio-frequency magnetron sputtering and of Sn1-xCaxSe are prepared by pulsed laser...
Resource Type:: Dissertation
Full Text:: alloys Sn1-xCaxCh (Ch= S, Se) and nitride compounds Zn-W-Mo-N, which have recently been predicted by

Development of Amorphous Metal Thin Films for Thermal Inkjet Printing and Microelectronics

Creator:: McGlone, John M.
Abstract:: Due to a lack of grain boundaries, an amorphous metal thin film (AMTF) possesses advantageous mechanical properties and enhanced chemical stability that is potentially useful for thermal inkjet (TIJ) printing applications. The use of an AMTF as a TIJ resistor or cavitation plate could lead to a thinner TIJ cavitation...
Resource Type:: Dissertation
Full Text:: process. Thank you to my Wager group peers, Kevin Stewart, Hans Chiang, Fan Zhou, and Greg Angelos. A

Applications of Holographic Optical Tweezers: Multiplexed Fluorescence Spectroscopy and the Micromechanics of Type-I Collagen

Creator:: Cibula, Matthew A.
Abstract:: The development and some applications of holographic optical tweezers (HOT) are presented. Our HOT system uses a spatial light modulator (SLM) to control the location and properties of the optical trap. We have developed a method for optimizing the diffraction efficiency of a SLM that can be applied in situ...
Resource Type:: Dissertation
Full Text:: ] w0 2 −2r2 I(r, z) = I0 exp . (2.18) w(z) w2(z) The width of the beam depends on its location

Comprehensive depletion-mode modeling of oxide thin-film transistors

Creator:: Zhou, Fan
Abstract:: The primary focus of this thesis is modifying the comprehensive depletion-mode model and extending its applicability to p-channel thin-film transistor (TFT) behavior and subthreshold (subpinchoff) operation. The comprehensive depletion-mode model accurately describes depletion-mode TFT behavior and establishes a set of equations, different from those obtained from square-law theory, which can...
Resource Type:: Masters Thesis
Full Text:: . I would like to thank all of my group members, Bao Yeh, Tsung Chiang, Kevin Archila, Kevin Stewart

ScholarsArchive@OSU

Analysis of the mechanism of sulfoxide-lithium exchange and the reactive intermediate in stereospecific reagent-controlled homologation (StReCH)

Total Synthesis of Isotopologues of Xanthohumol and its Congeners for Biological Studies

Synthesis and catalytic applications of derivatives of 7,7'-dihydroxy-8,8'-biquinolyl (azaBINOL)

Cis-2,5-diaminobicyclo[2.2.2]octane : a novel C₂-symmetric scaffold for asymmetric catalysis

Electronic and Optical Properties of Defects in Amorphous Oxide and Transition Metal Dichalcogenide Semiconductors

Total synthesis of sparteine alkaloids from a common tetraoxobispidine intermediate

Synthesis and Analysis of Heterostructural Semiconductor Alloy Sn1-xCaxCh (Ch=S, Se) and Nitrides Zn1-xWxN and Zn1-x(W1-yMoy)xN

Development of Amorphous Metal Thin Films for Thermal Inkjet Printing and Microelectronics

Applications of Holographic Optical Tweezers: Multiplexed Fluorescence Spectroscopy and the Micromechanics of Type-I Collagen

Comprehensive depletion-mode modeling of oxide thin-film transistors

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