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Filtering by: Creator Bond, F. Leroy Remove constraint Creator: Bond, F. Leroy Committee Member Ostroverkhova, Oksana Remove constraint Committee Member: Ostroverkhova, Oksana

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  • Gene Expression, Structure Elucidation, and Bioactivity of Aspergillus Natural Products

    Creator:
    Neuhaus, George F.
    Abstract:
    The study of natural products (NPs) and their application has shaped humanity. Starting with the idea of using plants as medicine, it has now grown into the science of purifying and identifying organic molecules from nature to study their inherent biological activities. Understanding the molecular structures of NPs is the...
    Resource Type:
    Dissertation
    Full Text:
    B97X-D3/def2-TZVP(-f) (shift: 20 nm; σ = 0.3 eV; ΔESI = 0.8165

  • Influence of processing parameters on diffusion of divalent nickel in wet silica sol-gel monoliths

    Creator:
    Dickson, David J.
    Abstract:
    The diffusion of divalent nickel (Ni²⁺) from wet silica gels was investigated. Silica gel is gaining interest as an encapsulation matrix for biological components. The transport of biologically relevant species within the gel is determined by the structural characteristics of the gel, which are in turn governed by synthesis parameters....
    Resource Type:
    Masters Thesis
    Full Text:
    – oxygen bonds assume a bond angle of 109.5° and Si – O – Si bonds are 144°. The Si – O b ond length is

  • Heterojunction Assisted Impact Ionization at the ZnS/Si Interface and Cu_10Te_4S_13 Photodiodes

    Creator:
    Reidy, Christopher F.
    Abstract:
    Several topics are presented in this dissertation, each of which has applications to solar cells and photodetectors. First, we discuss the growth of Cu10Te4S13, copper tellurium tetrahedrite. This material has interesting optical properties; it has a large joint density of states at the conduction band maximum and valence band minimum,...
    Resource Type:
    Dissertation
    Full Text:
    : 𝑓(𝜆) = { 0 𝜆 > 𝜆𝑔𝑎𝑝 𝐼(𝜆) ∙ [1

  • Total Synthesis of Isotopologues of Xanthohumol and its Congeners for Biological Studies

    Creator:
    Plagmann, Layhna S.
    Abstract:
    Xanthohumol [XN, (E)-6´-methoxy-3´-(3-methylbuten-2-yl)-2´,4´,4´´-trihydroxychalcone], the principal prenylated chalcone from hops, and its 2,3-dihydro- (DXN) and O6-desmethyl-2,3-dihydro- (DDXN) congeners, are of potential utility for the amelioration of metabolic syndrome; however, their complex bioactivity profiles cannot be properly studied and understood without access to appropriately produced synthetic materials. In the first part of...
    Resource Type:
    Masters Thesis
    Full Text:
    acetophenone enolate alkylation strategy was pursued to forge the central C2-C3 bond; however, this tactic

  • Label free biosensing with carbon nanotube transistors

    Creator:
    Leyden, Matthew R.
    Abstract:
    As electronics reach nanometer size scales, new avenues of integrating biology and electronics become available. For example, nanoscale field-effect transistors have been integrated with single neurons to detect neural activity. Researchers have also used nanoscale materials to build electronic ears and noses. Another exciting development is the use of nanoscale...
    Resource Type:
    Dissertation
    Full Text:
    capacitance of about 0.4 F/m 2 . 24 2.3 Carbon Nanotube Field-Effect Transistors (CNT FETs) This

  • Evaluation of amorphous oxide semiconductors for thin film transistors (TFTs) and resistive random access memory (RRAM) applications

    Creator:
    Rajachidambaram, Jaana Saranya
    Abstract:
    Thin-film transistors (TFTs) are primarily used as a switching element in liquid crystal displays. Currently, amorphous silicon is the dominant TFT technology for displays, but higher performance TFTs will become necessary to enable ultra-definition resolution high-frequency large-area displays. Amorphous zinc tin oxide (ZTO) TFTs were fabricated by RF magnetron sputter...
    Resource Type:
    Masters Thesis
    Full Text:
    staggered bottom gate structure is employed. F (C F d to a ch h ch igure 1.1: Fo C

  • Terahertz Imaging and Nonlinear Spectroscopy of Semiconductors using Plasmonic Devices

    Creator:
    Thompson, Zachary James
    Abstract:
    In this dissertation, a series of studies in the field of terahertz (THz) science are presented, specifically using nonlinear THz spectroscopy. We exploit huge field enhancement and subwavelength confinement in plasmonic structures. There are three distinct projects which will be discussed: nonlinear THz spectroscopy using plasmonic induced transparency (PIT), THz-triggered...
    Resource Type:
    Dissertation
    Full Text:
    Maxwell’s equations in matter. [25] ∇× E = −∂B ∂t (2.1) ∇×H = Jf + ∂D ∂t (2.2) ∇ ·D = ρf (2.3) ∇ ·B

  • Tracking Photoinduced Primary Events with Femtosecond Stimulated Raman Spectroscopy and Calculations

    Creator:
    Wang, Yanli
    Abstract:
    Femtosecond stimulated Raman spectroscopy (FSRS) is a powerful ultrafast technique which can track photoinduced excited state structural events on femtosecond (fs) to picosecond (ps) timescales. In addition to high temporal and spectral resolutions, FSRS provides a broad spectral window from ca. 100—2000 cm-1 for detection, enabling the direct mapping of...
    Resource Type:
    Dissertation
    Full Text:
    state photoacid (PA*) and photobase (PB*) forms of HPTS during ESPT. An intermolecular H-bond

  • Electronic and Optical Properties of Defects in Amorphous Oxide and Transition Metal Dichalcogenide Semiconductors

    Creator:
    Vogt, Kyle
    Abstract:
    The optical and electronic properties of amorphous oxide thin films depend crucially on chemical composition, and deposition process variations which give rise to sub-gap defect states. Consequently, there is a need for a reliable, high-throughput method to extract sub-gap defect densities of states in amorphous oxide thin films. We present...
    Resource Type:
    Dissertation
    Full Text:
    with an oxygen vacancy, it can form a metal-hydrogen (M-H) bond, thereby decreasing the oxygen

  • Expediting the Generation and Analysis of Amorphous Oxide Computational Models: Modeling Complex Systems Swiftly

    Creator:
    Buchanan, Jacob C.
    Abstract:
    In this dissertation, the process of computational modeling of amorphous oxide materials is studied. Amorphous oxides have random atomic arrangements with no long-range structural order which makes it difficult to study structure-property relationships. Despite the difficulties, amorphous oxides have great uses as semiconductors and dielectrics in thin-film transistors. The ability...
    Resource Type:
    Dissertation
    Full Text:
    larger number of atoms. A large amount of data can be generated from these model collections (i.e. bond