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Filtering by: Creator Jackson, Alexis M. Remove constraint Creator: Jackson, Alexis M. Contributor Huang, Yang Remove constraint Contributor: Huang, Yang Degree Field Chemistry Remove constraint Degree Field: Chemistry

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  • Stereocontrolled Synthesis of Allenes by Eliminative Cross-Coupling of Carbenoids

    Creator:
    Cao, Yang
    Abstract:
    The bimolecular reaction of two carbenoid species resulting in the formation of a carbon-carbon double bond (pi-system), referred to herein as carbenoid eliminative cross-coupling (CEXC), involves a series of three fundamental steps: (i) ate-complex formation (transmetalation), (ii) 1,2-metalate rearrangement, and (iii) beta-elimination. All three steps are stereospecific and so the...
    Resource Type:
    Dissertation
    Full Text:
    stereocenter of carbenoid (55) remains the same, the another stereocenter of R2 R1 M’ X’ R3 R4M X M