Index Catalog // ScholarsArchive@OSU

Start Over

Filtering by: Creator Minshew, Hudson F. Creator Balyeat, John Robert Degree Field Chemistry

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Creator:

Balyeat, John Robert

Abstract:

The tosylhydrazones of exo-3-deuteriocamphor and 2- deuterio-2,4-dimethy1-3-pentanone were treated with Nbromosuccinimide (NBS) and pyruvic acid to regenerate the parent ketones. The ketones from the pyruvic acid cleavage show a significant loss of deuterium. The ketones from the NBS cleavage show no loss of deuterium, indicating that stereochemical integrity at. C[subscript...

Resource Type:

Masters Thesis

Full Text:

migratory ratio Hx/Hn being 138. Kyba and Hudson have studied the behavior of what they term an "unbiased