The reaction conditions for the synthesis of Cu-BTC (BTC = benzene-1,3,5-tricarboxylic acid) were elucidated using a continuous-flow microreactor-assisted solvothermal system to achieve crystal size and phase control. A high-rate synthesis of Cu-BTC metal-organic frameworks with BET surface area of more than 1600 m²/g (Langmuir surface area of more than 2000...
Full Text:
:10.1039/c3cc46049e
10.1039/c3cc46049e
Royal Society of Chemistry
Accepted Manuscript
http
A novel method of copper indium diselenide nanoparticle
(CuInSe₂ NP) synthesis using a two-step, continuous flow,
solar microreactor is reported here. This method allows for
exceedingly fast heating and short reaction times using only
radiative heat transfer from simulated, concentrated solar
radiation. Chalcopyrite and sphalerite CuInSe₂ phases have
both been...
Combined plasmonic nanocrystals and metal–organic framework
thin-films are fabricated for sensing gases in the near-infrared
range. This nanocomposite thin-film shows a highly sensitive response
in near-infrared absorption, which is attributed to preconcentration
of gas molecules in metal–organic framework pores causing close
proximity to the electromagnetic fields at the plasmonic nanocrystal...
Full Text:
Chemistry
C, 3(12), 2763-2767. doi:10.1039/C4TC02846E
10.1039/C4TC02846E
Royal Society of Chemistry
Assembly of nanocrystals is considered one of the most promising approaches to design nano-, microstructures, and complex mesoscopic architectures. A variety of strategies to induce nanocrystal assembly have been reported, including directed assembly methods that apply external forces to fabricate assembled structures. In this study ZnO nanocrystals were synthesized in...