In this paper, we report a fiber-optic carbon dioxide (CO₂) near-infrared (IR) absorption sensor with only 8-cm sensing length that is coated with nanoporous metalorganic framework material Cu-BTC (BTC = benzene-1,3, 5-tricarboxylate). The multimode optical fiber was etched by hydrofluoric acid to remove the cladding and part of the core,...
Despite significant advantages in terms of portability and cost, near-infrared (NIR) gas sensing still remains a great challenge due to its relatively weak overtone absorption from the fundamental vibrational bond absorption at the mid-IR frequency. In this paper, we demonstrated ultra-sensitive NIR gas sensing for carbon dioxide (CO₂) at 1.57...
Converting CO2 to valuable materials is attractive.Herein, we report using simple metallothermic reactions to reduce atmospheric CO2 to dense nanoporous graphene. By using a Zn/Mg mixture as a reductant, the resulted nanoporous graphene exhibits highly desirable properties: high specific surface area of 1900 m2/g, a great conductivity of 1050 S/m...
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(2010) 480–483.
[11] Q. Li, R.R. Jiang, Y.Q. Dou, Z.X. Wu, T. Huang, D. Feng,
J.P. Yang, A.S. Yu, D.Y
Continuous microreactor-assisted solution deposition is demonstrated for the deposition
of CdS thin films on fluorine-doped tin oxide (FTO) coated glass. The continuous flow
system consists of a microscale T-junction micromixer with the co-axial water circulation
heat exchanger to control the reacting chemical flux and optimize the heterogeneous surface
reaction. Dense,...
Combined plasmonic nanocrystals and metal–organic framework
thin-films are fabricated for sensing gases in the near-infrared
range. This nanocomposite thin-film shows a highly sensitive response
in near-infrared absorption, which is attributed to preconcentration
of gas molecules in metal–organic framework pores causing close
proximity to the electromagnetic fields at the plasmonic nanocrystal...
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. S. Zhou, F. R. Fan, W. Zhang, Z. Y. Zhou, D. Y. Wu,
B. Ren, Z. L. Wang and Z. Q. Tian, Nature, 2010
The role of gold nanoparticles supported on ZnO in photocatalytic activity for dye degradation
was investigated. To do this, gold nanoparticles supported on ZnO (Au-ZnO) were prepared using a
simple co-precipitation method. The prepared nanocatalyst was characterized by high resolution
transmission electron microscopy, X-ray diffraction, temperature programmed reduction, X-ray
photoelectron...
The thermal oxidation of submicron metallic Zn particles was studied as a method to form nanostructured ZnO films. The particles used for this work were characterized by electron microscopy, x ray diffraction, and thermal analysis to evaluate the Zn-ZnO core shell structure, surface morphology, and oxidation characteristics. Significant nanostructural changes...
A continuous flow sonochemical reactor was developed capable of producing metastable cadmium sulfide (CdS) nanoplatelets with thicknesses at or below 10 nm. The continuous flow sonochemical reactor included the passive in-line micromixing of reagents prior to sonochemical reaction. Synthesis results were compared with those from reactors involving batch conventional heating...
The reaction conditions for the synthesis of Cu-BTC (BTC = benzene-1,3,5-tricarboxylic acid) were elucidated using a continuous-flow microreactor-assisted solvothermal system to achieve crystal size and phase control. A high-rate synthesis of Cu-BTC metal-organic frameworks with BET surface area of more than 1600 m²/g (Langmuir surface area of more than 2000...
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. Ahn, Chem. Commun., 2008, 6336-
6338; (b) Z.-Q. Li, L.-G. Qiu, T. Xu, Y. Wu, W. Wang, Z.-Y. Wu
and X
Compared to conventional amorphous silicon (a-Si) TFTs, amorphous metal oxide TFTs have superior device performance such as
higher mobility, better sub-threshold swing, and lower off-state current. Amorphous metal oxide TFTs have an additional advantage
on the device uniformity due to the lack of grain boundary issues in the poly-Si TFTs....