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Filtering by: Creator Wynne, Clive D. Creator Daruwala, Khushroo Peshotan Degree Field Chemistry

Substituent control in the oxy-Cope rearrangements of 1-vinyl-trans-cyclotridec-3-en-1-ol systems

Creator:

Daruwala, Khushroo Peshotan

Abstract:

The thermal and anionic rearrangements of substituted 1-vinyltrans- cyclotridec-3-en-l-ol compounds have been studied to determine what effects substituents would have on the sigmatropic shift when placed on the two positions of the 1-vinyl group. For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols gave both the [3,3] and [1,3] shift products of...

Resource Type:

Dissertation

Full Text:

diradical intermediate. D. L. J. Clive has devised a strategy involving repetitive ring expansion of