We, for the first time, employ magnesiothermic reaction to convert microwave-irradiated graphite oxide to pure graphene. The magnesiothermic reaction raises the carbon to oxygen atomic ratio from 22.2 to 165.7 and maintains a high surface area. The new strategy demonstrates an efficient method for obtaining highly pure graphene materials.
We introduce a novel ambient hydrolysis deposition (AHD) methodology that, for the first time, employs sequential water adsorption followed by a hydrolysis reaction to infiltrate tiny SnO2₂ particles inside nanopores of mesoporous carbon in a conformal and controllable manner. The empty space in the SnO2₂/C composites can be adjusted by...
Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In...
Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In...
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Bommier†, Zelang Jian†, XinLi†, Rich Carter†, Sean Vail‡, Yuhao Lu‡,
Jong-Jan Lee‡, Xiulei Ji
Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In...
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Oxide as a
Dehydration Agent
Wei Luo†, Clement Bommier†, Zelang Jian†, XinLi†, Rich Carter†, Sean
Despite the considerable advances of deposition technologies, it remains a significant challenge to form conformal deposition on surface of nanoporous carbons. Here, we introduce a new ambient hydrolysis deposition method that employs and controls pre-adsorbed water vapor on nanoporous carbons to define the deposition of TiO₂. We converted the deposited...
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. Xiong, Y. Jiang, F. Zou, X. Hu, Y. Xin,
Z. Zhang, Y. Huang, Energy Environ. Sci. 2013, 6, 2497-2504
Mg batteries have potential advantages in terms of safety, cost, and reliability
over existing battery technologies, but their practical implementations are hindered
by the lack of amenable high-voltage cathode materials. The development
of cathode materials is complicated by limited understandings of the unique
divalent Mg²⁺ ion electrochemistry and the interaction/transportation...
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viable candidates
for post Li-ion energy storage. Com-
pared with other widely pursued metal
anodes