We report zero kinetic energy (ZEKE) photoelectron spectroscopy of benzo[a]pyrene (BaP) via resonantly enhanced multiphoton ionization (REMPI). Our analysis concentrates on the vibrational modes of the first excited state (S₁) and those of the ground cationic state (D₀). Similar to pyrene, another peri-condensed polycyclic aromatic hydrocarbon we have investigated, the...
We compare characteristics of electron impact ionization (EI) and multiphoton ionization (MPI) of doped super fluid helium droplets using the same droplet source. Selected dopant ion fragments from the two ionization schemes demonstrate different dependence on the doping pressure, which could be attributed to the different ionization mechanisms. While EI...
We report a facile method of doping cations from an electrospray ionization (ESI) source into superfluid helium droplets. By decelerating and stopping the ion pulse of reserpine and substance P from an ESI source in the path of the droplet beam, about 10⁴ ion-doped droplets (one ion per droplet) can...
We report vibrational information of both the first electronically excited state and the ground
cationic state of jet-cooled triphenylene via the techniques of resonantly enhanced multiphoton
ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The first excited
electronic state S₁ of the neutral molecule is of A₁' symmetry and...
We present two facile time-of-flight (TOF) methods of detecting superfluid helium droplets and droplets with neutral dopants. Without an electron gun and with only a heated filament and pulsed electrodes, the electron impact ionization TOF mass spectrometer can resolve ionized helium clusters such as He₂ ⁺ and He₄ ⁺, which...
We present an experimental investigation of the effect of kinetic energy on the ion doping efficiency of superfluid helium droplets using cesium cations from a thermionic emission source. The kinetic energy of Cs⁺ is controlled by the bias voltage of a collection grid collinearly arranged with the droplet beam. Efficient...
We report electron diffraction of ferrocene doped in superfluid helium droplets. By taking advantage of the velocity slip in our pulsed droplet beam using a pulsed electron gun, and by doping with a high concentration of ferrocene delivered via a pulsed valve, we can obtain high quality diffraction images from...