The familiar equilibrium between 1, 7- octadiene and cyclooctene
at temperatures exceeding 3000, indicates that an ene-retroene
process could be used as a six atom ring expansion method. To test
this possibility we prepared both cis and trans isomers of 1, 2- diallyl-
1, 2 -bis (trimethylsiloxy) cyclohexane and pyrolyzed...