After three decades of active research in hydrology and stream ecology, the connection between solute transport, stream metabolism and nutrient dynamics is still unresolved. This existing gap obscures the functionality of stream ecosystems and how they interact with other landscape processes. To date, determining rates of metabolism is accomplished with...
We propose the experimental use of resazurin (Raz) and develop a metabolically active transient storage (MATS) model to include processes that may provide additional information on transient storage from a biogeochemical perspective in stream ecosystems. Raz is a phenoxazine compound that reduces irreversibly to resorufin (Rru) in the presence of...
We investigated scaling of conservative solute transport using temporal moment
analysis of 98 tracer experiments (384 breakthrough curves) conducted in 44 streams
located on five continents. The experiments span 7 orders of magnitude in discharge
(10⁻ ³ to 10³ m³/s), span 5 orders of magnitude in longitudinal scale (10¹ to...
Surface and subsurface flow dynamics govern residence time or water age until discharge, which is a key metric of storage and water availability for human use and ecosystem function. Although observations in small catchments have shown a fractal distribution of ages, residence times are difficult to directly quantify or measure...
Temperature is a fundamentally important driver of ecosystem processes in streams. Recent warming of terrestrial climates around the globe has motivated concern about consequent increases in stream temperature. More specifically, observed trends of increasing air temperature and declining stream flow are widely believed to result in corresponding increases in stream...
We investigated multiple-rate diffusion as a possible explanation for observed behavior in a suite of single-well injection-withdrawal (SWIW) tests conducted in a fractured dolomite. We first investigated the ability of a conventional double-porosity model and a multirate diffusion model to explain the data. This revealed that the multirate diffusion hypothesis/model...
Convergent flow tracer tests conducted in the Culebra dolomite (Rustler Formation, New Mexico) are analyzed with both single- and multiple-rate, double-porosity models. Parameter estimation is used to determine the mean and standard deviation of a lognormal distribution of diffusion rate coefficients as well as the advective porosity and longitudinal dispersivity....
In the 300 Area of a U(VI)-contaminated aquifer at Hanford, Washington, USA,
inorganic carbon and major cations, which have large impacts on U(VI) transport, change on
an hourly and seasonal basis near the Columbia River. Batch and column experiments were
conducted to investigate the factors controlling U(VI) adsorption/desorption by changing...
Estimates of mass transfer timescales from 316 solute transport experiments reported in 35 publications are compared to the pore-water velocities and residence times, as well as the experimental durations. New tracer experiments were also conducted in columns of different lengths so that the velocity and the advective residence time could...