Transport and structural properties of Mg-doped and O-intercalated sintered powders and
polycrystalline films of CuSc₁₋ₓMgₓO[subscript 2+y] are reported. Substitution of Mg for Sc systematically
increases the p-type conductivity in CuSc₁₋ₓMgₓO₂ sintered powders, producing a maximum
conductivity of 0.015 S/cm at x≈0.06. A similar level of conductivity is observed in transparent...
Double excitonic absorption peaks are observed in textured BaCuSF and BaCuSeF thin films. The excitonic doublet separation increases with increasing fraction of heavy chalcogen in the thin-film solid solutions, in good agreement with the spin-orbit splitting of the valence bands calculated by density-functional theory. In BaCuSF and BaCuSeF, the excitons...