Catalysis of the racemizationof optically active phenyl
benzenethiolsulfinate, (+)-I, by (a) methylthioacetic acid (II) and (b)
a -methylthio-m-toluic acid (III) has been investigated in aqueous
dioxane and anhydrous acetonitrile at 39.6°C. Added II did not cause
any increase in the rate of racemization of (+)-I in either solvent. In
aqueous...