New syntheses for 2-bicyclo(3.3.1)nonanone and 7-bicyclo-(3.3.1)nonen-2-one were developed. The saturated ketone was prepared
from phenol and acrylonitrile via a novel intramolecular
S[subscript N]2 cyclization process. A Friedel-Crafts cyclization of 3-(3-cyclohexenyl)propanoyl chloride permitted synthesis of the unsaturated
ketone from 4-cyclohexene carboxaldehyde. The formation of
the bicyclo(3.3.1)nonane rather than a bicyclo(3.2.2)nonane skeleton...
The utilization of extra-high-voltage underground power cables
over distances greater than 100 miles presents serious problems relative
to the voltage and current limits of such cables. These problems
are directly associated with the fixed amount of capacitance inherent
in long cable lines. As a result, large charging currents are
characteristic...
Longevity and germination of seed of western dwarfmistletoe (Arceuthobium campylopodum Engelm. f. campylopodum) of ponderosa
pine (Pinus ponderosa Laws.) was investigated to determine:
1) the influence of humidity and temperature on seed viability and
deterioration during storage; 2) the physiology of seed dormancy;
3) the composition of seed reserve food...
This study was undertaken to determine the sorts of polygalacturonases
present in the culture filtrate of Fusarium oxysporum
f. sp. lycopersici, to purify and characterize these enzymes, and to
study any complexes that may form between polygalacturonase and
carbohydrate not degraded by the enzyme.
The polygalacturonase in culture filtrate consists...
This dissertation describes a new radio-frequency power-amplifier circuit and mode of operation that exceeds the efficiency of the conventional class C amplifier in the low and medium h-f range. It will be found useful in applications where linearity between the input and output are not required, as in all applications...
The maximum principle developed by the Russian mathematician,
L.S. Pontryagin is considered to be one of the most significant
contributions to the recent advances in mathematical optimization
techniques.
Unfortunately, most of the published literature on the application
of the maximum principle is in the field of control system design,
and...
A waveform-preserving, variable time-delay system capable of
several milliseconds delay is described in this thesis. These considerably
long delays are achieved by judicious use of the relatively
low sonic velocity of gases. Initial system design criteria specified
a time delay of ten milliseconds and a signal bandwidth of 0-10 KC....
A sampling criterion which provides a numerical relationship
between sampling rate and worst-case peak error for linear interpolation
of sample points is presented. The criterion, based upon the
second derivative of a waveform, is derived, its properties are observed
for a sine wave, and its applicability to complex signals is...
It was observed that certain myoelectric surface
potentials are of a pulse nature. The pulses have nearly
the same exact waveshape, but are asynchronously
repetitive.
Physiological evidence indicated that myoelectric
pulses are concurrent with the activity of a small unit
of organized muscle fibres (motor unit). The electrical
activity of...
A method for measuring food carbon assimilation in the copepod
Calanus finmarchicus was developed, using the diatom Ditylum
brightwelli as food. The amount of particulate food carbon ingested
was determined as the difference between CHN analyzer analyses for
particulate food carbon of pre- and post-grazed food suspensions.
The fraction of...
An examination was made of some reactions involving a transfer
of carbon from boron to carbon. In the case of the reaction of
a C[subscript n] alkylorganoborane with dichlorocarbene the intermediate was
a C[subscript n]₊₁ chloroalkylorganoborane. Oxidation of this intermediate
yielded an homologous acid (33%) and the usual alcohol (66%)....
Douglas fir bark fines which contained 74.8 percent
of Klason lignin and 70.2 percent of one percent sodium
hydroxide solubility and decayed Douglas fir wood which
contained 53.9 percent of Klason lignin were subjected to
ethanolysis. A slight modification of the Hibbert's
ethanolysis procedure was used. The monomeric compounds
present...