The relative rates of bridgehead hydrogen abstraction from a
series of 1-substituted adamantanes by the trichloromethyl radical
at 40.0°C. has been carried out. Utilizing the Hammett-Taft equation
a p* value of -0.40 was obtained for this reaction. Application
of the Kirkwood-Westheimer model for the transmission of substituent
effects gave an...
Pseudomonas aeruginosa cells were selected for their ability
to grow in the presence of 750 ppm alkyldimethylethylbenzyl
ammonium chloride (QAC). These cells were found to retain their
resistance to the germicide throughout tri-weekly transfers for 7
months in tryptone glucose yeast extract (TGY) broth containing no
QAC. Comparisons of the...
A total of five individual experiments were conducted with
gonadectomized, male sheep to study the influence of estrogen on
the plasma level of pituitary activities, with the greatest emphasis
given to gonadotropic activity. Estrogen treatments employed were
as follows:
1. 12 mg. diethylstilbestrol (DES) implanted subcutaneously.
2. 1 mg. DES...
Contracting nucleolar vacuoles are a general and consistent
feature of somatic tobacco cells growing in microcultures. Nucleolar
vacuoles were studied in cells from callus tissues of two
single-cell clones, H-196 and H-239, of hybrid tobacco (Nicotiana
tabacum X N. glutinosa). Vacuoles periodically contracted either
completely or incompletely, apparently releasing a...
A study of the relative rates of the alkyl hydrogen abstraction
from a series of meta and para substituted t-butylbenzenes by the
chlorine atom at 70°C has been carried out. Application of the
Hammett equation yielded a ρ value of -0.44 for the para compounds.
Possible explanations for the non-linearity...
A study of the relative rates of benzylic hydrogen abstractions
from a series of meta and para substituted neopentylbenzenes by the
bromine radical and trichloromethyl radical at 70°C has been carried
out. Application of the Hammett equation yields p values of -0.75
for the bromine atom and -0.94 for the...
Digestibility experiments were carried out with dairy heifers to
determine the digestibility of orchard grass, Dactylis glomerata, and
also to evaluate the accuracy of various indicator techniques in pasture
digestibility experiments. Chromic oxide was used as an external
indicator to predict fecal dry matter output in three digestion
trials. Cut...