The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec-
3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone
(VII) and cyclopentadec-5-en-l-one (VIII) after
hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic
shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with
a concerted or diradical...
The thermal regime of a postulated descending lithospheric slab
is calculated. The gravity anomaly associated with such a structure
is large in amplitude and long in wavelengh. Observed free-air
gravity anomalies in the Pacific Northwest do not indicate a gravitational
effect due to a descending slab.
Two hypothetical compensation models...
A free-air gravity anomaly map of the area between 10°-17°N and
90°-101°W shows distinctive positive and negative anomalies which
parallel the Tehuatepec Ridge. The positive anomaly approximately
overlies the topographic expression of the ridge. On the wide continental
shelf southeast of the Gulf of Tehuantepec a positive gravity
anomaly with...
Gravity, magnetic and seismic data indicate that the oceanic
crust is 9.7 km thick west of the Continental Borderland. The top
of the mantle is about 12 km deep under the Borderland, and deepens
to 27 km beneath the Peninsular Ranges of Baja California. The
mantle is about 20 km...
Gravity and magnetic data from cruises by the R/V Yaquina in 1973
and the R/V Wecoma in 1975 provide new data that make possible the construction of a map of the free-air gravity anomalies at sea and simple
Bouguer anomalies on lano in Panama, western Colombia, and the eastern
Panama...
In order to quantitatively examine the crustal structure of the
Panama Basin without the benefit of local seismic refraction data, the
following assumptions were made: (1) No significant lateral changes
in density take place below a depth of 50 km. (2) The densities of the
crustal layers are those of...
Both oxy-Cope and siloxy-Cope rearrangements involve
(1, 3) and (3, 3) sigrnatropic shifts. Both the concerted mechanism,
and the stepwise mechanism via a diradical intermediate are possible.
In a cyclic system such as cis-l-vinylcyclooct-3-en-l-ol, the thermal
rearrangement takes place preferably through a diradical intermediate.
At high temperature, the reaction also...
An emmission sampling system was developed to measure pollutants
emitted from a mobile agricultural incinerator developed at
Oregon State University. The system was designed to collect a particulate
sample on an 8" x 10" fiber glass filter and collect a gaseous
sample in a plastic bag. Pollutants measured were particulates...
Part 1
The pyrolysis of cis-1-trimethylsiloxy-1-cyclopr opyl-3-cyclononene in the temperature range 285-350° is described. Instead
of siloxy-Cope rearrangement, undesired desiloxylation took place.
Part 2
Gas-phase pyrolytic rearrangement of 2-phenyl-1-trimethylsiloxy-1-vinylcyclononane was investigated in a static system
in the temperature range 213-330°. It was discovered that
three major products resulted: cis- and...