Carbonyl sulfide (COS) has been investigated as a rapid-equilibrium inhibitor of CO oxidation
by the CO dehydrogenase purified from Rhodospirillum rubrum. The kinetic evidence suggests that the
inhibition by COS is largely competitive versus CO (Ki = 2.3 pM) and uncompetitive versus methylviologen
as electron acceptor (Ki = 15.8 pM)....
Crystal rich (~ 70–98% phenocrysts) magmatic inclusions in pumices for compositionally heterogeneous ignimbrites from the Central Andes of northern Chile are interpreted as the products of crystal accretion at the sidewalls of the magma chambers. The inclusions are typically andesitic in composition and are found as ‘peppery textured’ lenses and...
The first seagoing test of a prototype laser/fiber-optic system for in situ detection of ocean chlorophyll fluorescence is described. Radiation at 488 nm originating from a shipboard argon laser was transmitted through 20 of 200-µm core optical fiber to the distal tip mounted on the microstructure profiler, the Rapid Sampling...
Twelve days of microstructure measurements at the equator (140°W) in November 1984 showed a
surprisingly strong effect of both the daily cycle of solar heating and wind on mixing in the upper ocean.
Because of limited variations in atmospheric forcing and currents during the experiment, processes in the
daily mixing...
Many of the processes that have important effects on both the climatological distribution and interannual variability of sea surface temperatures (SSTs) in the tropical oceans are greatly affected by the surface wind field. For this reason accurate simulation of the surface wind is a key factor governing the success of...
Lagrangian equations for momentum and buoyancy are developed for idealized turbulent fluid elements. The resulting formulation of transport can he viewed as a generalization of mixing length and parcel theories of mixing for application to gridded Eulerian models. This formulation of transport recognizes the mean gradients on the scale of...
The conventional view of equatorial dynamics requires that the zonal equatorial wind stress be balanced, in the mean, by the vertical integral of “large-scale” terms, such as the zonal pressure gradient, mesoscale eddy flux, and mean advection, over the upper few hundred meters. It is usually presumed that the surface...
The Kalman filter is implemented and tested for a simple model of sea level anomalies in the tropical Pacific, using tide gauge data from six selected island stations to update the model. The Kalman filter requires detailed statistical assumptions about the errors in the model and the data. In this...
In four dimensions, two metrics that are conformally related define the same Hodge dual operator on the space of two‐forms. The converse, namely, that two metrics that have the same Hodge dual are conformally related, is established. This is true for metrics of arbitrary (nondegenerate) signature. For Euclidean signature a...
A note of caution is Provided to users of the widely-distributed Cox ocean circulation model. It is shown that the discrete conservation of vorticity equation associated with the finite difference approximations to the primitive equations on an Arakawa B grid contains a term that approximates βΔy²∂²u/∂x∂y. Although this term has...