Electronic structure calculations for free and immersed atoms are performed in the context of unrestricted Hartree-Fock Theory. Spherical symmetry is broken, lifting de-generacies in electronic configurations involving the magnetic quantum number m. Basis sets, produced from density functional theory, are then explored for completeness. Com-parison to spectroscopic data is done...
Since 1958 when Alfred C. Redfield (1) recognized the similarity between the ratios of elements in living biomass and those dissolved in the surrounding seawater, we have understood that microorganisms largely control the concentrations, distribution, and molecular makeup of nutritional resources in the ocean. The primary elemental ingredients for life,...
Salmon survival and eventual recruitment success have long been thought to be determined within the first summer following ocean migration. Juvenile growth during this period is largely influenced by ocean conditions such as temperature, prey availability, abundance, and quality. Shifts in these conditions due to climatic perturbations are particularly prevalent...
Pesticides are among the most pervasive environmental contaminants and they are an important potential risk for human health. Agricultural workers are constantly exposed to pesticide spray, drift and residues in the soil and foliage. Many agricultural pesticides are readily absorbed by the body, through contact with the skin, the respiratory...
Managing rangelands with livestock grazing is a tool that can be applied to obtain vegetation management objectives. Animals utilize available resources, which vary in quantity and quality, across the landscape. Their movements are adjusted to the spatial and temporal heterogeneity of resource distribution. Controlling livestock distribution is fundamental to economically...
We studied the feasibility of using end-grain characteristics to match individual boards and cants back to their parent Douglas-fir (Pseudotsuga menziesii) logs. After reviewing marking/reading and biometric automated identification systems, we focused on end-grain biometrics because they appear to have the most promise for sawmills. Biometric identification requires that every...
Endothelial activation with increased expression of cellular adhesion molecules, chemokines and pro-inflammatory cytokines critically contributes to vascular inflammation and the initiation and progression of atherosclerosis. By affecting redox-sensitive cell signaling pathways and transcription factors, redox-active transition metal ions, such as copper and iron, may play an important role in these...
As the demand for real-time information in engineering and health care systems keeps increasing, the need for wireless sensor nodes is also continuously increasing. As a result, the cost and effort involved in installing and maintaining batteries to power the numerous sensor nodes is growing exponentially. Providing a cost effective...
Nest counts from the largest subpopulation of the loggerhead sea turtle (Caretta caretta) in the Atlantic, peninsular Florida, have been declining since 1998. Analyzing trends of nests and adult females is insufficient to determine the overall status of a sea turtle population, due to variation in nesting frequency and a...
Grapes (e.g. Vitis vinifera L.) are one of the more important fruit crops from an economic standpoint with world market values over 550 million US dollars in 2007 and 2008, second to apples (United States Department of Agriculture). While a satisfactory level of ripeness is of primary concern, the quality...