Many industrially important reactions use immobilized enzymes in non-aqueous, organic
systems, particularly for the production of chiral compounds such as pharmaceutical precursors.
The addition of a spacer molecule (“tether”) between a supporting surface and enzyme often
substantially improves the activity and stability of enzymes in aqueous solution. Most “long”
linkers...
We derive an approach to determine the causal direction of wavevectors of modes in optical metamaterials, which, in turn, determines signs of refractive index and impedance as a function of real and imaginary parts of dielectric permittivity and magnetic permeability. We use the developed technique to demonstrate that the interplay...
We evaluated whether bacteria with higher cell-specific nucleic acid content (HNA) or an active electron transport system, i.e., positive for reduction of 5-cyano-2,3-ditolyl tetrazolium chloride (CTC), were responsible for the bulk of bacterioplankton metabolic activity. We also examined whether the phylogenetic diversity of HNA and CTC-positive cells differed from the...
Mg/Ca ratios in planktonic foraminifera reflect calcification temperatures and are thus useful for sea
surface temperature (SST) reconstructions. Despite the obvious utility of this paleoceanographic tracer,
problems of dissolution, gametogenic calcification, and contaminant phases have thus far limited
confidence in Mg/Ca-based reconstructions. Here we show strong evidence of Mg heterogeneity...
Using a qualitative approach, the authors tested a crime
typology developed for tourism destinations in a U.S. National
Forest recreation setting. Specific objectives were to
classify the attributes of crime and violence, examine the effects
of crime and violence on visitor demand, and suggest
methods of prevention and recovery. A...
Advanced Very High Resolution Radiometer (AVHRR) 4-km data collected over the northeastern Atlantic off the coast of the Iberian Peninsula for May to August 1995 were used to investigate the feasibility of empirically deriving estimates of the aerosol indirect radiative forcing. A retrieval scheme was used to derive cloud visible...
Visible and near infrared reflectances from NOAA-14 Advanced Very High Resolution Radiometer (AVHRR) daytime passes are used to derive optical depths at 0.55 μm, an index of aerosol type, continental or marine, and the direct effect of the aerosol on the top of the atmosphere and surface solar radiative fluxes...
Atmospheric particulate matter, collected over the polluted east Asia/Pacific region in spring 2001 during research flights with the National Center for Atmospheric Research (NCAR) C-130 aircraft, was analyzed for different types of organic compounds using capillary gas chromatography–mass spectrometry. More than 70 organic species were detected in the aerosols and...
Hop (Humulus lupulus L.) is cultivated for the female flowers, or “cones,” which traditionally have been used as a bittering and flavoring agent in beer. Hop breeding historically relied on relatively simple selection techniques within established breeding lines. Supplementing current breeding material with new genetic sources would enhance a hop...
Analysis of the Bakota basalts exposed in the Zambezi Gorge some 40 km east of Victoria Falls characterizes them as high Fe, moderately high Ti, and low K, P, and Zr tholeiites. The ⁴⁰Ar-³⁹Ar age determinations are tightly clustered at 180-179 Ma. All of the lavas that were samples have...
We used mark-recapture methods to estimate age-specific apparent survival rates for male Lesser Prairie-Chickens (Tympanuchus pallidicinctus), a gamebird of conservation concern. A total of 311 male prairie-chickens (135 yearlings, 176 adults) were captured and banded during a 5-year study in southwest Kansas. Time-since-marking models were used to estimate apparent survival...
Two sources of systematic errors are considered for estimating air temperature. The first source is ambiguity of the definition of the standardized measurement height over vegetated surfaces of varying heights. Without such a standardization, evaluation of the horizontal air temperature gradient is contaminated by the vertical variation of air temperature....
The atmospheric response to the oceanic forcing in the eastern Pacific along the northern equatorial sea surface temperature (SST) front is investigated in terms of sensible and latent heat flux during the 6-month period from 28 July 1999 to 27 January 2000 and the 7-month period from 28 June 2000...
Air-sea interaction at ocean fronts and eddies exhibits positive correlation between sea surface temperature (SST), wind speed, and heat fluxes out of the ocean, indicating that the ocean is forcing the atmosphere. This contrasts with larger scale climate modes where the negative correlations suggest that the atmosphere is driving the...
The spatial and temporal variability of inner-shelf circulation along the central Oregon coast during the
2004 upwelling season is described using a 70-km-long array of moorings along the 15-m isobath. Circulation
at three stations located onshore of a submarine bank differed from that of a station north of the bank,...
The nonlinear dynamics of unstable alongshore currents in the nearshore
surf zone over variable barred beach topography are studied using numerical
experiments. These experiments extend the recent studies of Allen et al. [1996]
and Slnn et al. [1998], which utilized alongshore uniform beach topographies by
including sinusoidal alongshore variation to...
Shelf break conditions and alongshore flow off northwestern Australia are studied
during the strongly evaporative conditions of austral winter 2003. Present results,
along with those of previous authors, confirm that a poleward, fresh Leeuwin current core
is normally found near the shelf break. Salinity increases alongshore toward the
southwest. Although...
Surface transports into the California Current are calculated from TOPEX/POSEIDON altimeter surface height slopes during the 9.5 year period from October 1992–May 2002. These quantify the anomalous onshore and southward displacements of the water column during the 2000–2002 period, which had been hypothesized by others based on anomalous water properties...
Hydrologic processes control much of the export of organic matter and nutrients from
the land surface. It is the variability of these hydrologic processes that produces variable
patterns of nutrient transport in both space and time. In this paper, we explore how
hydrologic ‘‘connectivity’’ potentially affects nutrient transport. Hydrologic connectivity...
The ability of six climate models to capture the observed coupling between SST and surface wind stress in the vicinity of strong midlatitude SST fronts is analyzed. The analysis emphasizes air–sea interactions associated with ocean meanders in the eastward extensions of major western boundary current systems such as the Gulf...