In this thesis, we investigated the surface composition and orientation of both pure room-temperature ionic liquids (Ils) and binary mixtures of the ILs of the type consisting of the 1-alkyl-3-methylimidazolium ([C[subscropt n]mim]⁺, n=4, 8, and 12) cation coupled with either [PF₆]⁻, [BF₄]⁻, [Cl]⁻, or [Br]⁻. The surfaces of the ILs...
Engineered capillary barriers typically consist of two layers of granular materials designed so that the contrast in sediment hydrologic properties and sloping interface retains infiltrating water in the upper layer. We report here on the results of two bench-top capillary barrier experiments, and associated modeling. These experiments were conducted to...