An interlaboratory study of Mg/Ca and Sr/Ca ratios in three commercially available carbonate reference
materials (BAM RS3, CMSI 1767, and ECRM 752-1) was performed with the participation of
25 laboratories that determine foraminiferal Mg/Ca ratios worldwide. These reference materials containing
Mg/Ca in the range of foraminiferal calcite (0.8 mmol/mol to...
Since its discovery, the anomalous dielectric behavior of CaCu₃Ti₄O₁₂ (CCTO)
has drawn a great deal of attention for many possible applications in electronic
devices. The origin of the giant dielectric constant in CCTO was explained via an
internal barrier layer capacitor model, and it has been reported that the dielectric...
Previous research has shown a gap between chemistry students' conceptual
and computational understandings of chemistry topics such as gas laws,
equilibrium, and reactions. This qualitative study examined the conceptual and
computational understandings of stoichiometry of college students enrolled in a
large lecture Introductory Chemistry course. Factors that might influence students'...
The thermodynamic properties of 39 PBDEs have been calculated using Gaussian 03
on the B3LYP/6-31G(d)//B3LYP/6-31G(d) level. The PBDE congeners' enthalpies of
formation increase with increasing number of bromines and show a strong dependence on
the bromine substitution pattern. The effects of bromine substitution pattern have been
quantitatively studied by GAM...
Among recently found multi-component Zr-based bulk metallic glasses (BMG), Zr₅₈.₅Cu₁₅.₆Ni₁₂.₈Al₁₀.₃Nb₂.₈ is characterized by its lower critical cooling rate requirement and absence of beryllium as one of the constituent element which makes its handling more convenient. Its large supercooled liquid regions made possible the study of thermodynamics and kinetics of this...
The rhenium (V) complex Tp'ReO₂ (Tp' = hydrido-tris-(3,5-
dimethylpyrazolyl)borate), generated in situ from PPh₃ reduction of
Tp'Re0₃, reacts with small ring heterocycles such as epoxides and
episulf ides. The strained trans-cyclooctene ring provides an unusual
thermodynamic bias against direct atom transfer, but trans-cyclooctene
oxide still produces substantial amounts of trans-cyclooctene....
¹¹¹In/Cd perturbed angular correlation (PAC) gamma spectroscopy was used to
study the point defect thermodynamics of tetragonal zirconia (t-zirconia).
PAC can be used to measure, among other things, oxygen vacancy defect
concentrations in t-zirconia. Higher than expected concentrations of oxygen vacancies in
undoped samples were found using PAC. It was...
In situ, reduction of Cp*ReO₃ by PPh₃ to form (Cp*ReO)₂(μ-O)₂ allows catalytic deoxygenation of epoxides, however, conproportionation between Reⱽ and Reⱽᴵᴵ species to form clusters of ((Cp*Re)₃(μ-O)₆}²⁺(ReO₄⁻)2 and new compound {(Cp*Re)₃(μ²-O)₃(μ³-O⁾³ReO₃}⁺(ReO₄⁻) leads to removal of rhenium from the catalytic cycle and loss of activity, The epoxide deoxygenation mediated by (Cp*ReO)₂(μ-O)₂...
The objective of this thesis is to provide an initial demonstration of the feasibility of constructing highly transparent active electronic devices. Such a demonstration is successfully achieved in the fabrication of ZnO-based thin film transistors (TFTs) exhibiting transparency greater than ~90% in the visible portion of the electromagnetic spectrum and...
Due to the aluminum industry demands, a large effort has recently been devoted to the development of special alloys to be used as inert anodes for a newly designed aluminum reduction cell. The implementation of this new technology aims at the replacement of the graphite anodes that have been used...